THE UNSOLVATED PENTACHLOROFERRATE(III) ION - X-RAY CRYSTAL-STRUCTURE AND LOW-TEMPERATURE MAGNETISM OF TETRAMETHYLPIPERAZINIUM PENTACHLOROFERRATE(III)

被引：21

作者：

JAMES, BD

LIESEGANG, J

BAKALOVA, M

REIFF, WM

SKELTON, BW

WHITE, AH

机构：

[1] NORTHEASTERN UNIV,DEPT CHEM,BOSTON,MA 02115

[2] UNIV WESTERN AUSTRALIA,DEPT CHEM,NEDLANDS,WA 6009,AUSTRALIA

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 08期

关键词：

D O I：

10.1021/ic00112a017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Single-crystal X-ray diffraction study of the title compound, C8H20Cl5N2Fe, indicates crystallization in the monoclinic space group C2/c, Z = 4, with unit cell parameters a = 15.56(1) Angstrom, b = 8.876(3) Angstrom, c 12.487(6) Angstrom, and beta = 115.61(6)degrees, with a nearly ideal five-coordinate trigonal bipyramidal [FeCl5](2-) species in an ionic crystal lattice. A combination of Fe-57 Mossbauer spectroscopy and a.c. susceptometry confirms long-range magnetic order between 6 and 7 K with a 3-D antiferromagnetic ground state.

引用

收藏

页码：2054 / 2057

页数：4

相关论文

共 24 条

[1] MOSSBAUER SPECTRA OF IRON(3) DIKETONE COMPLEXES [J].

BANCROFT, GM ;

MADDOCK, AG ;

ONG, WK ;

PRINCE, RH ;

STONE, AJ .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1967, (12) :1966-&

[2] CRYSTAL AND MOLECULAR-STRUCTURES OF RINNEITE, SODIUM TRIPOTASSIUM HEXACHLOROFERRATE(II), AND HEXAAMMINECOBALT(III) HEXACHLOROFERRATE(III) - COMPARISON OF IRON CHLORIDE DISTANCES IN HEXACHLOROFERRATES(II) AND HEXACHLOROFERRATES(III) [J].

BEATTIE, JK ;

MOORE, CJ .

INORGANIC CHEMISTRY, 1982, 21 (04) :1292-1295

[3]

CARLIN RL, 1986, MAGNETOCHEMISTRY, pCH10

[4] ELECTRONIC AND MOLECULAR-STRUCTURE OF ANHYDROUS FERROUS ACETATE - WEAK ANTIFERROMAGNET CONTAINING 6-COORDINATE IRON(II) IN NONEQUIVALENT ENVIRONMENTS [J].

CHENG, C ;

REIFF, WM .

INORGANIC CHEMISTRY, 1977, 16 (08) :2097-2103

[5]

CREASER CS, 1979, J INORG NUCL CHEM, V41, P469

[6] PREPARATION, REACTIONS, AND SPECTROSCOPIC INVESTIGATION OF THE 1,1,3,3-TETRAMETHYLIMIDAZOLIDINIUM AND 1,1,4,4-TETRAMETHYLPIPERAZONIUM DICATIONS [J].

CREIGHTON, JA ;

TAYLOR, MJ .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1987, 65 (11) :2526-2528

[7] STRUCTURE OF A 5-CO-ORDINATE COMPLEX OF IRON - PENTA-AZIDOIRON(III) ION, FE(N3)52- [J].

DRUMMOND, J ;

WOOD, JS .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1969, (23) :1373-&

[8] CRYSTAL-STRUCTURE OF DIAMMONIUM AQUAPENTACHLOROFERRATE(III) [J].

FIGGIS, BN ;

RASTON, CL ;

SHARMA, RP ;

WHITE, AH .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1978, 31 (12) :2717-2720

[9] THE VISIBLE AND ULTRAVIOLET ABSORPTION SPECTRUM OF THE TETRACHLOROFERRATE (III) ION IN VARIOUS MEDIA [J].

FRIEDMAN, HL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1952, 74 (01) :5-10

[10] STRUCTURE, SPECTRA, AND MAGNETIC PROPERTIES OF CERTAIN IRON HALIDE COMPLEXES [J].

GINSBERG, AP ;

ROBIN, MB .

INORGANIC CHEMISTRY, 1963, 2 (04) :817-&