NEW SYNTHESIS OF 3-DEOXY-D-ERYTHRO-2-HEXULOSONIC ACID (2-KETO-3-DEOXYGLUCONIC ACID, KDG) FROM D-GLUCOSE

被引：15

作者：

PLANTIERROYON, R

ANKER, D

ROBERTBAUDOUY, J

机构：

[1] UNIV LYON 1, CHIM ORGAN LAB 3,CNRS,URA 467,BAT 303, 43 BD 11 NOVEMBRE 1918, F-69622 VILLEURBANNE, FRANCE

[2] INST NATL SCI APPL, GENET MOLEC MICROORGANISMES LAB, F-69621 VILLEURBANNE, FRANCE

来源：

JOURNAL OF CARBOHYDRATE CHEMISTRY | 1991年 / 10卷 / 02期

关键词：

D O I：

10.1080/07328309108543903

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

3-Deoxy-D-erythro-2-hexulosonic acid (KDG), an important metabolite of bacterial polysaccharides degradation was prepared from D-glucose in six steps via the synthesis of 2,4-O-isopropylidene-D-erythrose and subsequent Witting-Horner condensation followed by smooth deprotections of protecting groups. Overall yield was 35 % from D-glucose.

引用

页码：239 / 249

页数：11

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