MICROWAVE SPECTRA MOLECULAR STRUCTURE AND DIPOLE MOMENT OF PHOSPHIRANE

被引：56

作者：

BOWERS, MT

BEAUDET, RA

GOLDWHIT.H

TANG, R

机构：

[1] Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California

[2] Department of Chemistry, University of Southern California, Los Angeles

[3] Department of Chemistry, California State College at Los Angeles, Los Angeles, California

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 01期

关键词：

D O I：

10.1021/ja01029a003

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The microwave spectra of phosphirane, phosphirane-13C, cis- and trans-phosphirane-C-d1, and phosphirane-P-d have been studied. From these isotopes the following molecular structure was determined: r(C-C) = 1.502 A, r(C-P) = 1.867 Å, r(C-Hris) = 1.092 Å, r(C-Htrans) = 1.093 Å, r(P-H) = 1.428 Å, ZCPC = 47.4°, ZHCH = 114.4°, ZH-PQ(plane)] = 95.7°, ZH-P-C = 95.2°and ZC-C-Hcis = 118.0°, ZC-C-Htrans = 117.5°. A dipole moment of 1.12 D and its orientation were also obtained. © 1969, American Chemical Society. All rights reserved.

引用

页码：17 / +

页数：1

共 12 条

[1]

BEAUDET RA, 1962, THESIS HARVARD U

[2]

BOWERS MT, TO BE PUBLISHED

[3] THE MICROWAVE SPECTRA, STRUCTURE, AND DIPOLE MOMENTS OF ETHYLENE OXIDE AND ETHYLENE SULFIDE [J].