MICROWAVE SPECTRA MOLECULAR STRUCTURE AND DIPOLE MOMENT OF PHOSPHIRANE

被引：56
作者：
BOWERS, MT
BEAUDET, RA
GOLDWHIT.H
TANG, R
机构：
[1] Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California
[2] Department of Chemistry, University of Southern California, Los Angeles
[3] Department of Chemistry, California State College at Los Angeles, Los Angeles, California
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 01期
关键词：
D O I：
10.1021/ja01029a003
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The microwave spectra of phosphirane, phosphirane-13C, cis- and trans-phosphirane-C-d1, and phosphirane-P-d have been studied. From these isotopes the following molecular structure was determined: r(C-C) = 1.502 A, r(C-P) = 1.867 Å, r(C-Hris) = 1.092 Å, r(C-Htrans) = 1.093 Å, r(P-H) = 1.428 Å, ZCPC = 47.4°, ZHCH = 114.4°, ZH-PQ(plane)] = 95.7°, ZH-P-C = 95.2°and ZC-C-Hcis = 118.0°, ZC-C-Htrans = 117.5°. A dipole moment of 1.12 D and its orientation were also obtained. © 1969, American Chemical Society. All rights reserved.
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页码：17 / +
页数：1
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