DITERPENES FROM A KAEMPFERIA SPECIES

被引：26
作者：
PRAWAT, U
TUNTIWACHWUTTIKUL, P
TAYLOR, WC
ENGELHARDT, LM
SKELTON, BW
WHITE, AH
机构：
[1] SILPAKORN UNIV, FAC SCI, DEPT CHEM, NAKHON PATHOM 73000, THAILAND
[2] PHUKET TEACHERS COLL, DEPT CHEM, PHUKET 8300, THAILAND
[3] UNIV SYDNEY, DEPT ORGAN CHEM, SYDNEY, NSW 2006, AUSTRALIA
[4] UNIV WESTERN AUSTRALIA, SCH CHEM, NEDLANDS, WA 6009, AUSTRALIA
来源：
PHYTOCHEMISTRY | 1993年 / 32卷 / 04期
关键词：
KAEMPFERIA SP; ZINGIBERACEAE; PIMARADIENE DITERPENES;
D O I：
10.1016/0031-9422(93)85242-J
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Six novel diterpenes, sandaracopimaradien-9alpha-ol-1-one, sandaracopimaradien-1alpha,9alpha-diol, 6beta-acetoxysandaracopimaradien-9alpha-ol-1-one, sandaracopimaradien-6beta,9alpha-diol-1-one, 6beta-acetoxysandaracopimaradien-1alpha,9alpha-diol and sandaracopimaradien-1alpha,6beta,9alpha-triol have been isolated from the rhizomes of Kaempferia sp. The structures were assigned on the basis of their spectroscopic data and by chemical conversions. The crystal structures of the second and fifth compounds were also determined and the absolute stereochemistry of all the compounds established by CD methods.
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页码：991 / 997
页数：7
相关论文
共 17 条
[1]   NATURALLY OCCURRING TERPENE DERIVATIVES .117. NEW SANDARACOPIMARDIENE DERIVATIVES, SESQUITERPENES, AND SESQUITERPENE LACTONES FROM ZEXMENIA SPECIES [J].
BOHLMANN, F ;
LONITZ, M .
CHEMISCHE BERICHTE-RECUEIL, 1978, 111 (03) :843-852
[2]  
HERUNSALEE A, 1987, J SCI SOC THAILAND, V13, P119
[3]  
Ibers J. A., 1974, INT TABLES XRAY CRYS, VIV
[4]   CONSTITUENTS OF BOESENBERGIA-PANDURATA (SYN. KAEMPFERIA-PANDURATA) - ISOLATION, CRYSTAL-STRUCTURE AND SYNTHESIS OF (+1-)-BOESENBERGIN-A [J].
JAIPETCH, T ;
KANGHAE, S ;
PANCHAROEN, O ;
PATRICK, VA ;
REUTRAKUL, V ;
TUNTIWACHWUTTIKUL, P ;
WHITE, AH .
AUSTRALIAN JOURNAL OF CHEMISTRY, 1982, 35 (02) :351-361
[5]   FLAVONOIDS IN THE BLACK RHIZOMES OF BOESENBERGIA-PANDURATA [J].
JAIPETCH, T ;
REUTRAKUL, V ;
TUNTIWACHWUTTIKUL, P ;
SANTISUK, T .
PHYTOCHEMISTRY, 1983, 22 (02) :625-626
[6]   A UTERINE RELAXANT COMPOUND FROM ZINGIBER-CASSUMUNAR [J].
KANJANAPOTHI, D ;
SOPARAT, P ;
PANTHONG, A ;
TUNTIWACHWUTTIKUL, P ;
REUTRAKUL, V .
PLANTA MEDICA, 1987, (04) :329-332
[7]   CONSTITUENTS OF BOESENBERGIA-PANDURATA (SYN KAEMPFERIA PANDURATA) .3. ISOLATION AND SYNTHESIS OF (+/-)-BOESENBERGIN-B [J].
MAHIDOL, C ;
TUNTIWACHWUTTIKUL, P ;
REUTRAKUL, V ;
TAYLOR, WC .
AUSTRALIAN JOURNAL OF CHEMISTRY, 1984, 37 (08) :1739-1745
[8]   CONSTITUENTS OF BOESENBERGIA SP ISOLATION AND CRYSTAL-STRUCTURE OF CROTEPOXIDE ([1R-(1-ALPHA,2-ALPHA,4-ALPHA,5-BETA,6-ALPHA,4-ALPHA)]-4-[(BENZOYLOXY)METHYL]-3,8-DIOXATRICYCLO[5,1,0,02,4]OCTANE-5,6-DIYL DIACETATE) [J].
PANCHAROEN, O ;
PATRICK, VA ;
REUTRAKUL, V ;
TUNTIWACHWUTTIKUL, P ;
WHITE, AH .
AUSTRALIAN JOURNAL OF CHEMISTRY, 1984, 37 (01) :221-225
[9]   CYCLOHEXANE OXIDE DERIVATIVES FROM KAEMPFERIA-ANGUSTIFOLIA AND KAEMPFERIA SPECIES [J].
PANCHAROEN, O ;
TUNTIWACHWUTTIKUL, P ;
TAYLOR, WC .
PHYTOCHEMISTRY, 1989, 28 (04) :1143-1148
[10]   CRYSTAL-STRUCTURE OF PANDURATIN-A - (1'RS,2'SR,6'RS)-(2,6-DIHYDROXY-4-METHOXYPHENYL)-[3'-METHYL-2'-(3''-METHYLBUT-2'-ENYL)-6'-PHENYLCYCLOHEX-3'-ENYL]METHANONE [J].
PANCHAROEN, O ;
REUTRAKUL, V ;
SKELTON, BW ;
TAYLOR, WC ;
TUNTIWACHWUTTIKUL, P ;
WHITE, AH .
AUSTRALIAN JOURNAL OF CHEMISTRY, 1984, 37 (12) :2589-2592
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