STRUCTURE OF 4,5-(PENTASULFANE-1,5-DIYL)-1,3-DITHIOLE-2-THIONE

被引：9
作者：
BAUMER, VN
STARODUB, VA
BATULIN, VP
LAKIN, EE
KUZNETSOV, VP
DYACHENKO, OA
机构：
[1] RUSSIAN ACAD SCI,INST CHEM PHYS,CHERNOGOLOVKA 142432,RUSSIA
[2] KHARKOV AM GORKII STATE UNIV,INST CHEM,KHARKOV 310077,UKRAINE
[3] UKRAINIAN ACAD SCI,INST SINGLE CRYSTALS,KHARKOV 310001,UKRAINE
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷
关键词：
D O I：
10.1107/S0108270193004184
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
[1,3]Dithiolo[4,5-f]pentathiepine-7-thione, C3S8, M(r) = 292.5, triclinic, P1BAR, a = 4.4204(5), b = 9.136 (1), c = 11.762 (2) angstrom, alpha = 101.61 (1), beta = 96.20 (1), gamma = 92.28 (1)-degrees, V = 461.6 (1) angstrom , Z = 2, D(x) = 2.105 Mg M-3 , lambda(Mo Kalpha) = 0.71069 angstrom, mu = 1.790 mm-1, F(000) = 292, T = 290 K, R = 0.035, wR = 0.042 for 1170 observed reflections. The C3S8 molecule in the crystal has a local m symmetry and shows a chair conformation of the seven-membered ring containing five S and two C atoms. The central part of this ring makes dihedral angles of 68.6-degrees with the C3S5 group and 71.6-degrees with the terminal S3 group.
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页码：2051 / 2053
页数：3
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