STRUCTURE OF 4,5-(PENTASULFANE-1,5-DIYL)-1,3-DITHIOLE-2-THIONE

被引：9
作者：
BAUMER, VN
STARODUB, VA
BATULIN, VP
LAKIN, EE
KUZNETSOV, VP
DYACHENKO, OA
机构：
[1] RUSSIAN ACAD SCI,INST CHEM PHYS,CHERNOGOLOVKA 142432,RUSSIA
[2] KHARKOV AM GORKII STATE UNIV,INST CHEM,KHARKOV 310077,UKRAINE
[3] UKRAINIAN ACAD SCI,INST SINGLE CRYSTALS,KHARKOV 310001,UKRAINE
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷
关键词：
D O I：
10.1107/S0108270193004184
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
[1,3]Dithiolo[4,5-f]pentathiepine-7-thione, C3S8, M(r) = 292.5, triclinic, P1BAR, a = 4.4204(5), b = 9.136 (1), c = 11.762 (2) angstrom, alpha = 101.61 (1), beta = 96.20 (1), gamma = 92.28 (1)-degrees, V = 461.6 (1) angstrom , Z = 2, D(x) = 2.105 Mg M-3 , lambda(Mo Kalpha) = 0.71069 angstrom, mu = 1.790 mm-1, F(000) = 292, T = 290 K, R = 0.035, wR = 0.042 for 1170 observed reflections. The C3S8 molecule in the crystal has a local m symmetry and shows a chair conformation of the seven-membered ring containing five S and two C atoms. The central part of this ring makes dihedral angles of 68.6-degrees with the C3S5 group and 71.6-degrees with the terminal S3 group.
引用
收藏
页码：2051 / 2053
页数：3
相关论文
共 50 条
[21]   THE　SYNTHESIS　OF　4，5－BIS（4＇－BROMOBENZYLTHIO）－1，3－DITHIOLE－2－THIONE　WITH　ONE　DIMENSIONAL　INTERMOLECULAR　INTERACTIONS [J].
Fang QIInstitute of Crystal Materials Shandong University Jinan .
Chinese Chemical Letters, 1996, (02) :103-104
[22]   Alternative method for the preparation of 4,5-ethylenedithio-1,3-dithiole-2-thione and related compounds [J].
Papavassiliou, GC ;
Mousdis, GA ;
Papadima, A .
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2000, 55 (02) :231-232
[23]   THE ROLE OF CARBON MONOSULFIDE IN THE ELECTROCHEMICAL PREPARATION OF 4,5-BIS(METHYLTHIO)-1,3-DITHIOLE-2-THIONE [J].
MOLTZEN, EK ;
SENNING, A ;
HAZELL, RG ;
LUND, H .
ACTA CHEMICA SCANDINAVICA SERIES B-ORGANIC CHEMISTRY AND BIOCHEMISTRY, 1986, 40 (07) :593-597
[24]   The acid-catalysed rearrangements of 4,5-bis(2-thienylhydroxymethyl)-1,3-dithiole-2-thione [J].
Serebryakov, IM ;
Skabara, PJ ;
Perepichka, IF .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1999, (07) :1405-1410
[25]   Synthesis and crystal structure of a copper(I) coordination polymer with 4,5-bis(methylthio)-1,3-dithiole-2-thione ligand [J].
Fang, GS ;
Ji, Y ;
Wang, S ;
Zuo, JL ;
Bai, JF ;
You, XZ .
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2004, 20 (05) :603-607
[26]   4,5-Bis{2-[(benzothiazol-2-yl)sulfanyl]ethylsulfanyl}-1,3-dithiole-2-thione [J].
Chen, Jun-Qing ;
Hu, Pu-Zhou ;
Wang, Jian-Ge ;
Qu, Gui-Rong ;
Zhao, Bang-Tun .
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 :O5469-O5471
[27]   CONVENIENT SYNTHESIS OF 1,3-DITHIOLE-2-THIONE AND RELATED COMPOUNDS [J].
UENO, Y ;
NAKAYAMA, A ;
OKAWARA, M .
SYNTHESIS-STUTTGART, 1975, (04) :277-278
[28]   Structure and bonding of diiodine adducts of the sulfur-rich donors 1,3-dithiacyclohexane-2-thione (ptc) and 4,5-ethylenedithio-1,3-dithiole-2-thione (ttb) [J].
Bigoli, F ;
Deplano, P ;
Ienco, A ;
Mealli, C ;
Mercuri, ML ;
Pellinghelli, MA ;
Pintus, G ;
Saba, G ;
Trogu, EF .
INORGANIC CHEMISTRY, 1999, 38 (21) :4626-4636
[29]   Tribological properties of 4,5-di(cetyl thio)-1,3-dithiole-2-thione as additive in liquid paraffin [J].
Zhang, ZF ;
Liu, WM ;
Xue, QJ .
WEAR, 1997, 210 (1-2) :273-277
[30]   Magnesium-PVC Membrane Sensor Based on 4,5-Bis(Benzoylthio)-1,3-Dithiole-2-Thione [J].
Zamani, Hassan Ali ;
Nezhadali, Azizollah ;
Saghravanian, Malyheh .
ANALYTICAL LETTERS, 2008, 41 (14) :2727-2742
12345