2-(3,4-Dimethyl-5,5-dioxo-2H, 4H-pyrazolo[4,3-c][1,2]benzothiazin-2-yl)-N-(3-methoxybenzyl)acetamide

被引:1
作者
Ahmad, Matloob [1 ]
Siddiqui, Hamid Latif [2 ]
Zia-ur-Rehman, Muhammad [3 ]
Aslam, Sana [2 ]
Parvez, Masood [4 ]
机构
[1] Govt Coll Univ, Dept Chem, Faisalabad 38000, Pakistan
[2] Univ Punjab, Inst Chem, Lahore, Pakistan
[3] Applied Chem Res Ctr, PCSIR Labs Complex, Lahore 54600, Pakistan
[4] Univ Calgary, Dept Chem, Calgary, AB T2N IN4, Canada
关键词
data-to-parameter ratio = 14.6; mean ̄(C-C) = 0.002 Å; R factor = 0.036; single-crystal X-ray study; T = 173 K; wR factor = 0.098;
D O I
10.1107/S1600536812040226
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The asymmetric unit of the title compound, C21H22N4O4S, contains two molecules (A and B), in which the thiazine rings adopt an S-envelope conformation with the S atoms displaced by 0.621 (2) and 0.697 (2)angstrom from the mean planes formed by the remaining ring atoms. The dihedral angles between the N-methylacetamide groups and the methoxybenzene rings are 8.67 (10) and 54.49 (6)degrees in the two molecules and the equivalent torsion angles in the N-methylacetamide chains connecting the ring systems also differ. In the crystal, N-H center dot center dot center dot O hydrogen bonds connect the components into C(4) [100] chains of alternating A and B molecules. The packing is consolidated by weak C-H center dot center dot center dot O interactions, which generate a three-dimensional network.
引用
收藏
页码:O3064 / +
页数:16
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