A MASS-SPECTROMETRIC INVESTIGATION OF ION-MOLECULE EQUILIBRIA IN RBI, AGI, AND RBAG4I5 VAPORS - ENTHALPIES OF FORMATION OF IONS

被引：0

作者：

POGREBNOI, AM

KUDIN, LS

BURDUKOVSKAYA, GG

机构：

来源：

HIGH TEMPERATURE | 1992年 / 30卷 / 05期

关键词：

D O I：

暂无

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

Results of investigations of ion-molecule equilibria in RbI, AgI, and RbAg4I5 vapors are presented Enthalpies of formation of the ions (kJ/mole) are presented: 195 +/- 4 (Rb+ . RbI), -471 +/- 7 (I- .RbI), -68 +/- 8 (Rb+ .2RbI), 963 +/- 9 (Ag+ .AgI), -2.57 +/- 9 (I- .AgI), 200 +/- 25 (Rb+ .AgI .RbI), 539 +/- 10 (Rb+ .AgI), 669 +/- 10 (Ag+ .RbI), 926 +/- 20 (Ag+ .2AgI), and 330 +/- 25 (Ag+ -2RbI). It is shown that Ag+ ions, which are found to exist in the experiment, are nonequilibrium entities. The problems related to the lack of equilibrium nature of Ag+ ions are discussed.

引用

页码：745 / 752

页数：8

共 34 条

[11] Mass-spectrometric study on ion-molecule reactions of CH5+, C2H5+, and C3H5+ with benzoic acid and benzoates
Tsuji, M
Arikawa, T
Tanaka, Y
Nishimura, Y
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2000, 73 (07) : 1673 - 1684
[12] HIGH-PRESSURE MASS-SPECTROMETRIC STUDY OF ION-MOLECULE REACTIONS IN C2H5F AND C2H5CL
TAN, HS
PABST, MJK
FRANKLIN, JL
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES, 1976, 21 (3-4): : 297 - 315
[13] Mass-spectrometric study on ion-molecule reactions of CH5+, C2H5+ and C3H5+ with anilines, nitrobenzene, and benzonitrile
Tsuji, M
Arikawa, T
Nishimura, Y
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1999, 72 (02) : 293 - 301
[14] KINETIC MASS SPECTROMETRIC INVESTIGATION OF ION-MOLECULE REACTIONS OCCURRING IN C4 AND C5 ALKANES FOLLOWING PHOTOIONIZATION AT 106.7 AND 104.8 NM
SIECK, LW
SEARLES, SK
AUSLOOS, P
JOURNAL OF RESEARCH OF THE NATIONAL BUREAU OF STANDARDS SECTION A-PHYSICS AND CHEMISTRY, 1971, A 75 (03): : 147 - +
[15] Mass-spectrometric determination of formation enthalpies of gaseous ions of EuCl($MIN)3/, EuCl$+($MIN)4, and Eu 2Cl($MIN)7
Kudin, L.S.
Burdukovskaya, G.G.
Butman, M.F.
Krasnov, K.S.
Zhurnal Fizicheskoj Khimii, 1993, 67 (04):
[16] ENTHALPIES OF FORMATION OF THE NEGATIVE-IONS MNO2-, MNO3- AND MNO4- AS DETERMINED BY THE ION-MOLECULE EQUILIBRIUM METHOD
RUDNYI, EB
KAIBICHEVA, EA
SIDOROV, LN
RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 1993, 7 (09) : 800 - 804
[17] Mass-spectrometric study on ion-molecule reactions of CH5+, C2H5+, and C3H5+ with monosubstituted benzenes carrying a hydroxy group
Tsuji, M
Arikawa, T
Nishimura, Y
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2000, 73 (01) : 131 - 145
[18] Mass-spectrometric study on ion-molecule reactions of CH5+, C2H5+, and C3H5+ with monosubstituted benzenes carrying a carbonyl group
Tsuji, M
Nishimura, Y
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1998, 71 (01) : 273 - 283
[19] MASS-SPECTROMETRIC STUDY OF SATURATED VAPOR COMPOSITION OVER NEODYMIUM CHLORIDES .2. ION-MOLECULAR EQUILIBRIUM AND ENTHALPIES OF FORMATION OF POSITIVE AND NEGATIVE-IONS
KUDIN, LS
POGREBNOI, AM
BURDUKOVSKAYA, GG
ZHURNAL FIZICHESKOI KHIMII, 1993, 67 (05): : 908 - 914
[20] Mass-spectrometric study on ion-molecule reactions of CH5+, C2H5+ and C3H5+ with C9-C19 alkylbenzenes in an ion trap
Tanaka, Y
Tsuji, M
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2002, 75 (02) : 241 - 252

← 1 2 3 4 →