A MASS-SPECTROMETRIC INVESTIGATION OF ION-MOLECULE EQUILIBRIA IN RBI, AGI, AND RBAG4I5 VAPORS - ENTHALPIES OF FORMATION OF IONS

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作者：
POGREBNOI, AM
KUDIN, LS
BURDUKOVSKAYA, GG
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来源：
HIGH TEMPERATURE | 1992年 / 30卷 / 05期
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O59 [应用物理学];
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摘要：
Results of investigations of ion-molecule equilibria in RbI, AgI, and RbAg4I5 vapors are presented Enthalpies of formation of the ions (kJ/mole) are presented: 195 +/- 4 (Rb+ . RbI), -471 +/- 7 (I- .RbI), -68 +/- 8 (Rb+ .2RbI), 963 +/- 9 (Ag+ .AgI), -2.57 +/- 9 (I- .AgI), 200 +/- 25 (Rb+ .AgI .RbI), 539 +/- 10 (Rb+ .AgI), 669 +/- 10 (Ag+ .RbI), 926 +/- 20 (Ag+ .2AgI), and 330 +/- 25 (Ag+ -2RbI). It is shown that Ag+ ions, which are found to exist in the experiment, are nonequilibrium entities. The problems related to the lack of equilibrium nature of Ag+ ions are discussed.
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页码：745 / 752
页数：8
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