AN ALCOHOL RECOGNITION MOTIF - CLEAR EVIDENCE OF BINDING-SITE COOPERATIVITY IN THE COMPLEXATION OF CYCLOHEXANEDIOLS BY NEUTRAL POLYAZA-CLEFTS

被引：20

作者：

BELL, DA ^{[1
]}

DIAZ, SG ^{[1
]}

LYNCH, VM ^{[1
]}

ANSLYN, EV ^{[1
]}

机构：

[1] UNIV TEXAS,DEPT CHEM & BIOCHEM,AUSTIN,TX 78712

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 24期

基金：

美国国家科学基金会;

关键词：

MOLECULAR RECOGNITION; ALCOHOLS; CYCLITOLS; COOPERATIVE BINDING;

D O I：

10.1016/0040-4039(95)00715-O

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A polyaza-cleft is found to bind a variety of alcohol functional groups via two hydrogen bonds. The tethering of two clefts yields cooperativity between binding sites.

引用

页码：4155 / 4158

页数：4

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