NEUTRON-DIFFRACTION STUDY ON THE INTERCALATION OF DEUTEROPYRIDINE INTO TANTALUMDISULFIDE

被引：41

作者：

RIEKEL, C ^{[1
]}

FISCHER, CO ^{[1
]}

机构：

[1] HAHN MEITNER INST KERNFORSCH BERLIN GMBH,D-1000 BERLIN 39,FED REP GER

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1979年 / 29卷 / 02期

关键词：

D O I：

10.1016/0022-4596(79)90222-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The intercalation of C5D5N into the lattice of 2HTaS2 was followed by neutron powder diffraction using deuteropyridine as liquid phase. Disordered second-stage nuclei were found to initiate the reaction. Model calculations established that the nuclei contain about 30% first-stage layers and that the pyridine orientations are identical in the first- and second-stage compounds. Tracer exchange measurements indicate two pyridine fractions. © 1979.

引用

页码：181 / 190

页数：10

共 21 条

[1] CHEMICAL-REACTIONS OF TAS2 (H-2 PHASE) [J].

ACRIVOS, JV ;

DELIOS, C ;

KURASAKI, H .

PHILOSOPHICAL MAGAZINE, 1976, 34 (06) :1047-1056

[2]

ACRIVOS JV, 1975, J PHYS CHEM-US, V79, P3003, DOI 10.1021/j100593a043

[3]

ACRIVOS JV, 1973, ELECTRONS FLUIDS NAT, P341

[4] THE DIFFUSION AND SORPTION OF WATER IN ZEOLITES .2. INTRINSIC AND SELF-DIFFUSION [J].

BARRER, RM ;

FENDER, BEF .

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1961, 21 (1-2) :12-24

[5] ELECTRON MICROSCOPY AND DIFFRACTION OF LAYERED, SUPERCONDUCTING INTEERCALATION COMPLEXES [J].

FERNANDEZMORAN, H ;

OHSTUKI, M ;

HIBINO, A ;

HOUGH, C .

SCIENCE, 1971, 174 (4008) :498-+

[6] INTERCALATION COMPLEXES OF LEWIS BASES AND LAYERED SULFIDES - LARGE CLASS OF NEW SUPERCONDUCTORS [J].

GAMBLE, FR ;

OSIECKI, JH ;

CAIS, M ;

PISHARODY, R .

SCIENCE, 1971, 174 (4008) :493-+

[7]

HOHLWEIN D, 1972, THESIS U HAMBURG

[8] THE SYSTEM TANTALUM SULFUR [J].

JELLINEK, F .

JOURNAL OF THE LESS-COMMON METALS, 1962, 4 (01) :9-15

[9] MOLYBDENUM AND NIOBIUM SULPHIDES [J].

JELLINEK, F ;

BRAUER, G ;

MULLER, H .

NATURE, 1960, 185 (4710) :376-377

[10] CHARACTERIZATION OF GRAPHITE-FECL3 COMPOUNDS AS PARTLY ORDERED LAYER STRUCTURES [J].

METZ, W ;

HOHLWEIN, D .

CARBON, 1975, 13 (02) :87-96

← 1 2 3 →