MEASUREMENT OF SELF-DIFFUSION COEFFICIENTS IN EXTRACTANT SYSTEMS USING THE FT-NMR TECHNIQUE

被引:3
作者
WARNHEIM, T [1 ]
PAATERO, EYO [1 ]
机构
[1] SWEDISH UNIV ABO,IND CHEM LAB,SF-20500 ABO 50,FINLAND
关键词
DIFFUSION - Measurements - MATHEMATICAL TRANSFORMATIONS - Fourier Transforms - NUCLEAR MAGNETIC RESONANCE;
D O I
10.1016/0304-386X(87)90046-6
中图分类号
TF [冶金工业];
学科分类号
0806 ;
摘要
The Fourier-transform NMR pulsed field gradient spin-echo method was applied to the measurement of the self-diffusion coefficients of the active components in the commercial extractants LIX65N, LIX63 and Cyanex 272. CCl//4 and CDCl//3 were used as solvents. The self-diffusion coefficients in 0. 16 M CDCl//3 solutions are 8. 2, 9. 2 and 6. 7 multiplied by 10** minus **1**0 m**2 s** minus **1, respectively.
引用
收藏
页码:129 / 134
页数:6
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