A detailed kinetic study of ammonia oxidation

被引：64
作者：
Lindstedt, RP
Lockwood, FC
Selim, MA
机构：
[1] Department of Mechanical Engineering, Imperial College of Science, Technology and, Medicine, London, SW72BX, Exhibition Road
来源：
COMBUSTION SCIENCE AND TECHNOLOGY | 1995年 / 108卷 / 4-6期
关键词：
ammonia flame chemistry; SNCR; NOx formation;
D O I：
10.1080/00102209508960400
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
A comprehensive study of ammonia oxidation in laminar flames and flow reactors using detailed chemical kinetic modelling is reported. A flat premixed NH3/NO flame and counterflow CO/O-2/N-2 and CH4/O-2/N-2 diffusion flames doped with ammonia have been studied along with NH3/NO/O-2 and NH3/NO/O-2/C2H6 flow reactors. Available kinetic data has been reviewed and a detailed reaction mechanism for the C/N system is proposed and results from computations are compared with experimental data. The destruction and formation of NO is found to be dominated by NH2, NH and N radicals in most of the cases studied. It is shown that the relative significance of the different NHi radicals in the various NO formation channels depends entirely on the flame conditions and that the role of the amidogen is crucial in nitric oxide reduction.
引用
收藏
页码：231 / 254
页数：24
相关论文
共 72 条
[1]  
ANDERSEN P, 1982, 19 S INT COMB COMB I, P11
[2]  
[Anonymous], 1984, J CHEM PHYS
[3]   KINETIC-STUDIES OF THE GAS-PHASE REACTIONS OF CN WITH O-2 AND H-2 FROM 294-K TO 1000-K [J].
ATAKAN, B ;
JACOBS, A ;
WAHL, M ;
WELLER, R ;
WOLFRUM, J .
CHEMICAL PHYSICS LETTERS, 1989, 154 (05) :449-453
[4]   KINETIC MEASUREMENTS AND PRODUCT BRANCHING RATIO FOR THE REACTION NH2+NO AT 294-1027 K [J].
ATAKAN, B ;
JACOBS, A ;
WAHL, M ;
WELLER, R ;
WOLFRUM, J .
CHEMICAL PHYSICS LETTERS, 1989, 155 (06) :609-613
[5]  
Atakan B., 1992, 24 S INT COMB COMB I, P691, DOI 10.1016/S0082-0784(06)80085-8
[6]   EVALUATED KINETIC AND PHOTOCHEMICAL DATA FOR ATMOSPHERIC CHEMISTRY SUPPLEMENT-IV - IUPAC SUBCOMMITTEE ON GAS KINETIC DATA EVALUATION FOR ATMOSPHERIC CHEMISTRY [J].
ATKINSON, R ;
BAULCH, DL ;
COX, RA ;
HAMPSON, RF ;
KERR, JA ;
TROE, J .
JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1992, 21 (06) :1125-1568
[7]   EVALUATED KINETIC DATA FOR COMBUSTION MODELING [J].
BAULCH, DL ;
COBOS, CJ ;
COX, RA ;
ESSER, C ;
FRANK, P ;
JUST, T ;
KERR, JA ;
PILLING, MJ ;
TROE, J ;
WALKER, RW ;
WARNATZ, J .
JOURNAL OF PHYSICAL AND CHEMICAL REFERENCE DATA, 1992, 21 (03) :411-734
[8]  
BIAN J, 1990, 23RD S INT COMB PITT, P379
[9]  
BIAN J, 1986, 21ST S INT COMB PITT, P953
[10]  
BOSCO SR, 1984, J CHEM PHYS, V81, P3505, DOI 10.1063/1.448078
12345678