(1-Methyl-1H-imidazole-kappa N-3)(1-methyl-2-nitrosobenzene-kappa N)(5,10,15,20-tetra-phenylporphyrinato-kappa N-4)iron(II)dichloromethane monosolvate

被引：1

作者：

Abucayon, Erwin G. ^{[1
]}

Awasabisah, Dennis ^{[1
]}

Powell, Douglas R. ^{[1
]}

Richter-Addo, George B. ^{[1
]}

机构：

[1] Univ Oklahoma, Dept Chem & Biochem, 101 Stephenson Pkwy, Norman, OK 73019 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷

基金：

美国国家科学基金会;

关键词：

data-to-parameter ratio = 18.3; disorder in main residue; mean σ(C-C) = 0.003 Å; R factor = 0.056; single-crystal X-ray study; some non-H atoms missing; T = 100 K; wR factor = 0.173;

D O I：

10.1107/S160053681400083X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The solvated title compound, [ Fe(C44H28N4)(C4H6N2)(C7H7 NO)]center dot CH2Cl2, is a porphyrin complex containing an octahedrally coordinated FeII atom with 1-methylimidazole [Fe-N = 2.0651 (17) angstrom] and o-nitrosotoluene ligands at the axial positions. The o-nitrosotoluene ligand is N-bound to iron(II) [Fe-N = 1.8406 (18) angstrom and Fe-N-O = 122.54 (14)degrees]. The axial N-Fe-N linkage is almost linear, with a bond angle of 177.15 (7)degrees. One phenyl group of the porphyrin ligand is disordered over two orientations in a 0.710 (3):0.290 (3) ratio. The dichloromethane solvent molecule was severely disordered and its contribution to the scattering was removed with the SQUEEZE routine.

引用

页码：M51 / +

页数：14

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