CHELATION OF FLUORIDE-ION BY F2C(SF3)2 - FORMATION OF A 4-MEMBERED CS2F HETEROCYCLE WITH A SYMMETRICALLY BRIDGING FLUORIDE

被引:12
|
作者
VIETS, D
HEILEMANN, W
WATERFELD, A
MEWS, R
BESSER, S
HERBSTIRMER, R
SHELDRICK, GM
STOHRER, WD
机构
[1] UNIV BREMEN,INST ANORGAN & PHYS CHEM,LEOBENER STR NW2,W-2800 BREMEN 33,GERMANY
[2] UNIV GOTTINGEN,INST ANORGAN CHEM,W-3400 GOTTINGEN,GERMANY
[3] UNIV BREMEN,INST ORGAN CHEM,W-2800 BREMEN 33,GERMANY
关键词
D O I
10.1039/c39920001017
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the solid state CF2(SF3)2 adds F- with formation of a stable symmetrically bridged anion F2C(mu-SF3... )2F1-, the structure of the caesium salt of which has been determined by X-ray crystallography.
引用
收藏
页码:1017 / 1019
页数:3
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