A NEW METHOD FOR RECOVERING WASTE ALKALINE PERFLUORO-NORMAL-BUTANESULFONATE

被引：6

作者：

CONTE, L ^{[1
]}

NAPOLI, M ^{[1
]}

SCIPIONI, A ^{[1
]}

GUERRATO, A ^{[1
]}

机构：

[1] SICIT SPA,I-36072 CHIAMPO,ITALY

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1991年 / 53卷 / 02期

关键词：

D O I：

10.1016/S0022-1139(00)82346-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new method for recovering perfluoro-n-butanesulfonic acid from its waste alkaline salts and re-converting it into the corresponding 2,2,2-trifluoroethyl ester alkylating agent is described. Alkaline perfluoro-n-butanesulfonate can be converted into the corresponding acid by treating it with gaseous HCl in methanol; perfluoro-n-butanesulfonic acid is then directly esterified by treatment with 2,2,2-trifluoroethanol in thionyl chloride. Easy procedures and high yields could make this method important for industrial application, with possible economic and environmental benefits.

引用

页码：277 / 283

页数：7