EFFECTS OF NO AND SOLIDS ON THE OXIDATION OF METHANE TO FORMALDEHYDE

被引：45
作者：
IRUSTA, S
LOMBARDO, EA
MIRO, EE
机构：
[1] Instituto de Investigationes en Catálisis y Petroquímica-INCAPE, FIQ, UNL-CONICET, Santa Fe, 3000
来源：
CATALYSIS LETTERS | 1994年 / 29卷 / 3-4期
关键词：
FORMALDEHYDE; GAS-PHASE REACTIONS; METHANE PARTIAL OXIDATION; OXIDE CATALYSTS; NITRIC OXIDE;
D O I：
10.1007/BF00807113
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The selective oxidation of methane has been studied both in the presence and absence of solids (inert or catalysts) with and without NO added, at 1 bar of total pressure. NO enhances the yield to formaldehyde, while the solids favor its decomposition. These results, together with abundant literature data, show a maximum for formaldehyde yield of about 4.0%.
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页码：339 / 348
页数：10
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