RHODIUM-MEDIATED 100-PERCENT REGIOSELECTIVE OXIDATIVE HYDROAMINATION OF ALPHA-OLEFINS

被引：52

作者：

BRUNET, JJ ^{[1
]}

NEIBECKER, D ^{[1
]}

PHILIPPOT, K ^{[1
]}

机构：

[1] INST NATL POLYTECH TOULOUSE,F-31077 TOULOUSE,FRANCE

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 24期

关键词：

D O I：

10.1016/S0040-4039(00)79252-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The system generated from lithium anilide and [(Et3P)2RhCl]2 catalyzes (turnover 21) the regioselective condensation of aniline with styrene to give a mixture of PhNH-CH(CH3)Ph (hydroamination product) and PhN=C(CH3)Ph (oxidative hydroamination product) in c.a.1/2 ratio. This 100% regioselective oxidative hydroamination has been confirmed in the case of 1-hexene.

引用

页码：3877 / 3880

页数：4

共 14 条

[1]

BOLDRINI GP, 1974, SYNTHESIS-STUTTGART, P733

[2] FUNCTIONALIZATION OF ALKENES - CATALYTIC AMINATION OF MONOOLEFINS [J].