MODELING THE CHLORINE NITRATE NU-4 VIBRATION-ROTATION BAND

被引：6
作者：
CARTEN, KP
LOVEJOY, RW
机构：
[1] Chemistry Department, Lehigh University, Bethlehem
来源：
JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER | 1991年 / 46卷 / 06期
关键词：
D O I：
10.1016/0022-4073(91)90028-O
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
Changes in rotational constants for the nu-4 band of (ClONO2)-Cl-35 near 780 cm-1 were determined using a computer program for asymmetric top molecules. Using known ground-state rotational constants, the upper-state rotational constants were determined to be A' = 0.40361(4), B' = 0.0923(4) and C' = 0.07532(4) cm-1. Line wavenumbers and J quantum numbers for the modeled spectrum were correlated with experimental room-temperature i.r. spectra of ClONO2 at 0.1 cm-1 resolution. There was good agreement found between the modeled and experimental results.
引用
收藏
页码：513 / 517
页数：5
相关论文
共 12 条
  • [1] STRATOSPHERIC TRACE GASES IN THE SPRING 1986 ANTARCTIC ATMOSPHERE
    FARMER, CB
    TOON, GC
    SCHAPER, PW
    BLAVIER, JF
    LOWES, LL
    [J]. NATURE, 1987, 329 (6135) : 126 - 130
  • [2] Herzberg G, 1945, MOL SPECTRA MOL STRU
  • [3] HILLMAN JJ, 1990, COMMUNICATION
  • [4] INFRARED-SPECTROSCOPY OF THE LOWER STRATOSPHERE WITH A BALLOON-BORNE CRYOGENIC FOURIER SPECTROMETER
    KUNDE, VG
    BRASUNAS, JC
    CONRATH, BJ
    HANEL, RA
    HERMAN, JR
    JENNINGS, DE
    MAGUIRE, WC
    WALSER, DW
    ANNEN, JN
    SILVERSTEIN, MJ
    ABBAS, MM
    HERATH, LW
    BUIJS, HL
    BERUBE, JN
    MCKINNON, J
    [J]. APPLIED OPTICS, 1987, 26 (03): : 545 - 553
  • [5] LEVI BG, 1988, PHYS TODAY, V7, P17
  • [6] INFRARED SPECTRA OF ISOTOPIC HALOGEN NITRATES
    MILLER, RH
    BERNITT, DL
    HISATSUNE, IC
    [J]. SPECTROCHIMICA ACTA PART A-MOLECULAR SPECTROSCOPY, 1967, A 23 (02): : 223 - +
  • [7] TENTATIVE IDENTIFICATION OF THE 780-CM-1 NU-4 BAND Q-BRANCH OF CHLORINE NITRATE IN HIGH-RESOLUTION SOLAR ABSORPTION-SPECTRA OF THE STRATOSPHERE
    RINSLAND, CP
    GOLDMAN, A
    MURCRAY, DG
    MURCRAY, FJ
    BONOMO, FS
    BLATHERWICK, RD
    DEVI, VM
    SMITH, MAH
    RINSLAND, PL
    [J]. JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1985, 90 (ND5) : 7931 - 7943
  • [8] ROLAND FS, 1989, AM SCI, V77, P36
  • [9] SCHMEISSER M, 1980, Z NATURFORSCH B, V35, P1143
  • [10] MILLIMETER WAVE SPECTRUM OF CHLORINE NITRATE
    SUENRAM, RD
    LOVAS, FJ
    [J]. JOURNAL OF MOLECULAR SPECTROSCOPY, 1984, 105 (02) : 351 - 359
12