MODELING THE CHLORINE NITRATE NU-4 VIBRATION-ROTATION BAND

被引：6

作者：

CARTEN, KP

LOVEJOY, RW

机构：

[1] Chemistry Department, Lehigh University, Bethlehem

来源：

JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER | 1991年 / 46卷 / 06期

关键词：

D O I：

10.1016/0022-4073(91)90028-O

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

Changes in rotational constants for the nu-4 band of (ClONO2)-Cl-35 near 780 cm-1 were determined using a computer program for asymmetric top molecules. Using known ground-state rotational constants, the upper-state rotational constants were determined to be A' = 0.40361(4), B' = 0.0923(4) and C' = 0.07532(4) cm-1. Line wavenumbers and J quantum numbers for the modeled spectrum were correlated with experimental room-temperature i.r. spectra of ClONO2 at 0.1 cm-1 resolution. There was good agreement found between the modeled and experimental results.

引用

页码：513 / 517

页数：5

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