Collisional excitation of K atoms by rare gases and diatomic molecules: Correlation with electronic structure

被引：60

作者：

Anderson, R. W. ^{[1
]}

Aqutlanti, V. ^{[1
]}

Herschbach, D. R. ^{[1
]}

机构：

[1] Harvard Univ, Dept Chem, Cambridge, MA 02138 USA

来源：

CHEMICAL PHYSICS LETTERS | 1969年 / 4卷 / 01期

关键词：

D O I：

10.1016/0009-2614(69)85018-9

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Excitation of K* (4(2)P) has been studied as a function of collision energy by measuring K* fluorescence as a fast K beam (25 to 600 eV), produced by charge-exchange of an arcelerated K+ beam, traverses a target gas. Results obtained for the rare gases and for H-2, O-2, N-2, and Cl-2 suggest that the qualitative form of the excitation cross section is governed primarily by the lowest-lying vacant orbital in the target species.

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页码：5 / 8

页数：4

相关论文

共 24 条

[1]

AMDUR I, 1966, ADV CHEM PHYS, V10, P29

[2] Total cross sections for charge transfer between alkali atoms and halogen molecules [J].

Baede, A. P. M. ;

Moutlnho, A. M. C. ;

De Fries, A. E. ;

Los, J. .

CHEMICAL PHYSICS LETTERS, 1969, 3 (07) :530-531

[3] RESONANT SCATTERING OF ELECTRONS BY MOLECULES [J].

BARDSLEY, JN ;

MANDL, F .

REPORTS ON PROGRESS IN PHYSICS, 1968, 31 :471-&

[4] Penning ionization electron spectroscopy: Ionization of mercury [J].

Cermak, V. ;

Herman, Z. .

CHEMICAL PHYSICS LETTERS, 1968, 2 (06) :359-362

[5] DIPOLE-DIPOLE SCATTERING IN MOLECULAR BEAMS . VARIATION OF TOTAL CROSS SECTION WITH VELOCITY AND ROTATIONAL OVERLAP [J].

CROSS, RJ ;

GISLASON, EA ;

HERSCHBACH, DR .

JOURNAL OF CHEMICAL PHYSICS, 1966, 45 (10) :3582-+

[6] VIBRATIONAL EXCITATION AND FRAGMENTATION OF MOLECULAR HYDROGEN FROM SLOW K+ COLLISIONS [J].

DITTNER, PF ;

DATZ, S .

JOURNAL OF CHEMICAL PHYSICS, 1968, 49 (04) :1969-&

[7] GROSS FAILURE OF CONVENTIONAL ADIABATIC CRITERION STRUCTURE AND COHERENCE IN LOW-ENERGY EXCITATION OF HELIUM ATOMS BY HELIUM IONS [J].

DWORETSK.S ;

NOVICK, R ;

SMITH, WW ;

TOLK, N .

PHYSICAL REVIEW LETTERS, 1967, 18 (22) :939-&

[8]

Gilmore F. R., 1965, J QUANT SPECTRY RADI, V5, P369, DOI DOI 10.1016/0022-4073(65)90072-5

[9]

HELBING RKB, IN PRESS

[10] UNTERSUCHUNGEN UBER DIE ERZEUGUNG UND DEN NACHWEIS VON ALKALIATOMSTRAHLEN IM ENERGIEBEREICH ZWISCHEN 6 UND 4000 EV [J].

HOLLSTEIN, M ;

PAULY, H .

ZEITSCHRIFT FUR PHYSIK, 1966, 196 (04) :353-+