NOVEL ASPECTS OF DNP AND SNP

被引：9

作者：

BAGRYANSKAYA, EG ^{[1
]}

SAGDEEV, RZ ^{[1
]}

机构：

[1] INT TOMOG CTR,NOVOSIBIRSK,RUSSIA

来源：

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS | 1993年 / 180卷

关键词：

CIDNP; DNP; RADICAL REACTIONS; PHOTOLYSIS; MICELLE;

D O I：

10.1524/zpch.1993.180.Part_1_2.111

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The paper concerns applications of the dynamic (DNP) and stimulated (SNP) nuclear polarization method to the solution of various photochemical problems. The results of investigation of exchange interaction in radical pairs localized in micelles of different size have been summarized. The effect of weak field DNP in degenerate electron exchange reactions has been applied to measure the rate constants of electron exchange and to study CIDEP and mechanisms of photochemical reactions.

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收藏

页码：111 / 134

页数：24

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