ASYMMETRIC TOTAL SYNTHESIS FROM CYCLOPENTENE-1,2-DIONES - CHARACTERIZATION OF A DIASTEREOMERICALLY PURE MICHAEL ADDUCT

被引：4

作者：

BROWN, RT

FORD, MJ

机构：

[1] Chemistry Department, The University, Manchester

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 14期

关键词：

D O I：

10.1016/S0040-4039(00)88907-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A key cyclopentenolone intermediate in the asymmetric synthesis of alkaloids and seco-iridoids has been prepared from reaction of a chiral 5, 7-dioxoperhydro-1,4-oxazepine with a cyclopentene-1,2-dione dimer; the absolute configuration at the induced chiral centres has been assigned from n.O.e. experiments. © 1990.

引用

页码：2029 / 2032

页数：4

共 9 条

[1]

BEDDOES R, 1990, UNPUB

[2]

BLACKSTOCK WP, 1984, TETRAHEDRON LETT, P1831

[3] A STEREOSELECTIVE TOTAL SYNTHESIS OF (+/-)-DIHYDROSECOLOGANIN AGLUCONE [J].