AS-SPRAY-DEPOSITED STRUCTURE OF AN AL-20SI-5FE OSPREY PREFORM AND ITS DEVELOPMENT DURING SUBSEQUENT PROCESSING

The application of the Osprey process to the fabrication of newly developed Al-20Si-X alloys is at present a subject of considerable interest. This paper reports the results of a study on the as-spray deposited structural characteristics of an Al-20Si-5Fe alloy preform and their development during subsequent hot extrusion and high-temperature exposure, by means of X-ray diffraction, differential scanning calorimetry and electron microscopy. It is shown that in the as-spray-deposited preform of the alloy an unusual increase in the lattice parameter of the aluminium matrix was detected, which persisted throughout the processing. No evidence of supersaturation in the preform aluminium matrix could be found, which is considered to be associated with the characteristics of solidification and subsequent decomposition of the hypereutectic alloy during spray deposition, this allows the extensive formation of second phases and thus a substantial decrease in the solute enrichment of the solution. A metastable intermetallic phase, identified as delta-Al4FeSi2, together with silicon phase, was present as the predominant dispersed phase in the preform, and its transformation into the equilibrium phase, beta-Al5FeSi, through a peritectic reaction under the equilibrium conditions, must have been effectively suppressed during the Osprey process. The delta-phase initially with a platelet shape was fragmented into short rods during the extrusion subsequent to to spray deposition, while a part of this phase was transformed into the equilibrium beta-phase under the combined influence of heat and deformation. The refinement of the delta-phase, on the other hand, was found to decrease its metastability and thus to promote its decomposition during subsequent annealing at 400-degrees-C. The coexistence of the high volume fractions of the intermetallic and silicon phases in the extruded material greatly modified its restoration kinetics, resulting in a partially recrystallized microstructure, after prolonged soaking at 400-degrees-C for 100 h. Also shown is a peculiar microstructure of the as-spray-deposited material with numerous spherical colonies of 10-20-mu-m, characterized by the finer silicon particles and delta-phase platelets in their interior and occasionally decorated with micropores at their peripheries. These colonies are considered to originate from the remains of very fine droplets and particles in the larger droplets, which are presolidified in flight and then partially remelted at the deposition surface. The colonies were mixed up with the rest of the microstructure and the micropores closed by applying an extrusion operation.