THE CYCLING PROPERTIES OF THE LIXNI1-YCOYO2 ELECTRODE

被引：334

作者：

DELMAS, C ^{[1
]}

SAADOUNE, I ^{[1
]}

ROUGIER, A ^{[1
]}

机构：

[1] UNIV BORDEAUX 1,ECOLE NATL SUPER PHYS & CHIM,F-33405 TALENCE,FRANCE

来源：

JOURNAL OF POWER SOURCES | 1993年 / 44卷 / 1-3期

关键词：

D O I：

10.1016/0378-7753(93)80208-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The LiNiO2-LiCoO2 system exhibits a complete solid solution. These materials crystallize in the rhombohedral system with a layered structure. They have been used as positive electrode in lithium batteries. Up to 0.5 lithium atom can be reversibly deintercalated in the 3.5 to 4.0 V potential range. The highest specific energy (close to 500 W h/kg) is obtained in the LixNi0.7Co0.302 system. Moreover, the very small volume change upon deintercalation increased their interest for application point of view.

引用

页码：595 / 602

页数：8

共 17 条

[1] STUDY OF THE NAXCRO2 AND NAXNIO2 SYSTEMS BY ELECTROCHEMICAL DESINTERCALATION
BRACONNIER, JJ
DELMAS, C
HAGENMULLER, P
[J]. MATERIALS RESEARCH BULLETIN, 1982, 17 (08) : 993 - 1000
[2] BRACONNIER JJ, 1983, THESIS U BORDEAUX 1
[3] CHANG SH, 1989, CR ACAD SCI II, V308, P475
[4] STRUCTURE AND ELECTROCHEMISTRY OF LI1+/-YNIO2 AND A NEW LI2NIO2 PHASE WITH THE NI(OH)2 STRUCTURE
DAHN, JR
VONSACKEN, U
MICHAL, CA
[J]. SOLID STATE IONICS, 1990, 44 (1-2) : 87 - 97
[5] ELECTROCHEMICAL INTERCALATION OF SODIUM IN NAXCOO2 BRONZES
DELMAS, C
BRACONNIER, JJ
FOUASSIER, C
HAGENMULLER, P
[J]. SOLID STATE IONICS, 1981, 3-4 (AUG) : 165 - 169
[6] DUTTA G, UNPUB J SOLID STATE
[7] ALKALI METAL NICKEL OXIDES OF THE TYPE MNIO2
DYER, LD
BORIE, BS
SMITH, GP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1954, 76 (06) : 1499 - 1503
[8] SOME MAGNETIC AND CRYSTALLOGRAPHIC PROPERTIES OF THE SYSTEM LIX+NI1-2X++NIX+++O
GOODENOUGH, JB
WICKHAM, DG
CROFT, WJ
[J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1958, 5 (1-2) : 107 - 116
[9] SOLID-SOLUTION OXIDES FOR STORAGE-BATTERY ELECTRODES
GOODENOUGH, JB
MIZUSHIMA, K
TAKEDA, T
[J]. JAPANESE JOURNAL OF APPLIED PHYSICS, 1980, 19 (03) : 305 - 313
[10] CHEMICAL AND ELECTROCHEMICAL DEINTERCALATIONS OF THE LAYERED COMPOUNDS LICRO2,LICOOZ AND NACRO2,NAFEO2,NACOO2,NANIO2
MIYAZAKI, S
KIKKAWA, S
KOIZUMI, M
[J]. SYNTHETIC METALS, 1983, 6 (2-3) : 211 - 217

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