GEL FREE POLYMERIZATION OF N,N'-METHYLENEBISACRYLAMIDE INITIATED BY A PEROXODIPHOSPHATE THIOACETAMIDE REDOX SYSTEM - A KINETIC-STUDY

被引：2
作者：
BEHARI, K
AGRAWAL, U
DAS, R
机构：
[1] Polymer Laboratory, Chemistry Department, University of Allahabad, Allahabad
来源：
POLYMER JOURNAL | 1993年 / 25卷 / 10期
关键词：
GEL FREE; POLYMERIZATION; N; N'-METHYLENEBISACRYLAMIDE; PEROXODIPHOSPHATE-THIOACETAMIDE; REDOX; KINETICS;
D O I：
10.1295/polymj.25.1007
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The kinetics of polymerization of the divinyl monomer, i.e., N,N'-methylenebisacrylamide has been studied employing a peroxodiphosphate-thioacetamide redox system under inert atmosphere at 40+/-1-degrees-C. The rate of polymerization R(p), was proportional to [Monomer]1, [Thioacetamide]1.0, and [Peroxodiophosphate]0.5. Based on the experimental results, cyclopolymerization of the growing radicals and mutual termination has been proposed.
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页码：1007 / 1013
页数：7
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