SYNTHESIS AND CRYSTAL AND MOLECULAR-STRUCTURE OF H3(MU-ETA-2-C6H4) (MU-ETA-2-HC3NC6H5)OS3(CO)8

被引:17
作者
ADAMS, RD
GOLEMBESKI, NM
机构
[1] Department of Chemistry, Yale University, New Haven
关键词
D O I
10.1016/S0022-328X(00)81051-7
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The complex H3(μ-η2-C6H4) (μ-η2-HC3NC6H5)Os3(CO)8 has been synthesized and characterized by IR, 1H NMR and X-ray crystal structure analyses. The compound contains a dihapto-benzyne ligand bridging one edge of a triangular cluster of osmium atoms and a dihapto-formimidoyl ligand bridging a different edge on the opposite face of the cluster from the benzyne ligand. © 1979.
引用
收藏
页码:239 / 249
页数:11
相关论文
共 11 条
[1]   ISOCYANIDE INSERTION REACTIONS - ROLE OF ISOCYANIDE INSERTIONS IN METAL ASSISTED HYDROGENATION OF ISOCYANIDES [J].
ADAMS, RD ;
GOLEMBESKI, NM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (14) :4622-4623
[2]  
ADAMS RN, UNPUBLISHED
[3]   OXIDATIVE ADDITION-REACTIONS OF TRIPHENYLPHOSPHINE WITH DODECACARBONYL-TRIOSMIUM(O) - BENZENE-COMPLEXES, PHENYL-COMPLEXES AND RELATED COMPLEXES OF OSMIUM [J].
BRADFORD, CW ;
MASON, R ;
GAINSFORD, GJ ;
GUSS, JM ;
NYHOLM, RS ;
IRELAND, PR .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1972, (02) :87-+
[4]   OXIDATIVE ADDITION-REACTIONS OF TRIPHENYLPHOSPHINE WITH DODECACARBONYLTRIOSMIUM [J].
BRADFORD, CW ;
NYHOLM, RS .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (05) :529-533
[5]   NEUTRAL, CATIONIC, AND DICATIONIC RUTHENIUM(II) COMPLEXES OF SECONDARY CARBENES CHNH(P-C6H4CH3) AND CHN(CH3)(P-C6H4CH3) [J].
CHRISTIA.DF ;
ROPER, WR .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1974, 80 (02) :C35-C38
[6]   OXIDATION OF ALCOHOL TO COORDINATED CARBOXYLATE WITH A DIOXYGEN COMPLEX OF RUTHENIUM - EXAMPLES OF REVERSIBLE HYDROGEN TRANSFER TO AN ISOCYANIDE LIGAND [J].
CHRISTIAN, DF ;
CLARK, GR ;
WHITTLE, KR ;
WATERS, JM ;
ROPER, WR .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1972, (08) :458-+
[7]   CHEMISTRY OF METAL-HYDRIDES .17. ISOCYANIDE INSERTION INTO PT-H BOND, AND FORMIMIDOYL LIGAND [J].
CHRISTIAN, DF ;
CLARK, HC ;
STEPANIAK, RF .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 112 (02) :209-225
[8]  
CHRISTIAN DF, 1975, J CHEM SOC DA, P2556
[10]   OXIDATIVE ADDITION-REACTIONS IN CLUSTER COMPLEXES OF OSMIUM - INTRACLUSTER REACTIONS OF BENZYNE AND A NOVEL PHENYL COMPLEX [J].
GAINSFORD, GJ ;
MASON, R ;
IRELAND, PR ;
GUSS, JM ;
BRADFORD, CW ;
NYHOLM, RS .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1972, 40 (02) :C70-+