PHOTOOXIDATIONS OF SULFENIC ACID-DERIVATIVES .2. A REMARKABLE SOLVENT EFFECT ON THE REACTIONS OF SINGLET OXYGEN WITH DISULFIDES

被引：30

作者：

CLENNAN, EL

WANG, DY

ZHANG, HW

CLIFTON, CH

机构：

[1] Department of Chemistry University of Wyoming, Laramie

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 27期

关键词：

D O I：

10.1016/S0040-4039(00)76951-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Photooxidations of a series of 9 disulfides reveal that the thiosulfinate/thiosulfonate product ratios can be dramatically influenced by the nature of the solvent. The unique ability of methanol to influence this ratio is attributed to nucleophilic addition to a thiopersulfoxide intermediate.

引用

页码：4723 / 4726

页数：4

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