(Acetylacetonato-kappa O-2,O') bis[2-(5-methyl-3-phenylpyrazin-2-yl-kappa N-1) phenyl-kappa C-1]iridium(III)

被引：0

作者：

Ge, Guo-Ping ^{[1
]}

Li, Chun-Yan ^{[1
]}

Gu, Cheng-Hao ^{[1
]}

Li, Mao-He ^{[1
]}

Xu, Xiao-Nan ^{[1
]}

机构：

[1] Ningbo Univ, Fac Mat Sci & Chem Engn, Inst Solid Mat Chem, State Key Lab Base Novel Funct Mat & Preparat Sci, Ningbo 315211, Zhejiang, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

关键词：

data-to-parameter ratio = 14.4; mean σ(C-C) = 0.007 Å; R factor = 0.031; single-crystal X-ray study; T = 295 K; wR factor = 0.062;

D O I：

10.1107/S1600536812006022

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title complex, [Ir(C 17H 13N 2) 2(C 5H 7O 2)], the Ir III atom is hexa-coordinated in a distorted octa-hedral geometry by two C,N-bidentate 2-(5-methyl-3-phenylpyrazin-2-yl)phenyl (mdpp) ligands and one O,O-bidentate acetylacetonate ligand. The dihedral angles between the phenyl rings and the pyrazine ring are 9.56 (14) and 58.99 (14)° for one mdpp ligand and 9.34 (14) and 79.94 (15)° for the other.

引用

页码：M306 / U794

页数：11

共 11 条

[1] High-efficiency fluorescent organic light-emitting devices using a phosphorescent sensitizer [J].