THEORETICAL ASPECTS OF PHOTOCHEMICAL SUBSTITUTION OF (MN(CO)5CL) AND RELATED COMPLEXES

被引：9

作者：

PIERLOOT, K ^{[1
]}

HOET, P ^{[1
]}

VANQUICKENBORNE, LG ^{[1
]}

机构：

[1] UNIV LOUVAIN,DEPT CHEM,CELESTIJNENLAAN 200F,B-3001 HEVERLEE,BELGIUM

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1991年 / 09期

关键词：

D O I：

10.1039/dt9910002363

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A self-consistent field analysis of the photolysis of [Mn(CO)5Cl] has been performed. Based on electron-density difference plots and population analysis a correlation is made between the nature of the photoactive state and the preferential leaving ligand. The stereochemistry of the photolysis reaction has been determined by a study of the possible excited-state isomerization pathways of the five-co-ordinated structure [Mn(CO)4Cl]. The analysis confirms the experimentally observed trans --> cis stereopreference.

引用

页码：2363 / 2369

页数：7

共 34 条

[1]

ALLEN WF, 1974, INORG CHEM, V13, P905

[2]

ATTWOOD JD, 1976, J AM CHEM SOC, V98, P3160

[3]

ATTWOOD JD, 1975, J AM CHEM SOC, V97, P3380

[4] STUDIES OF THERMAL-INTERCONVERSIONS AND PHOTO-INTERCONVERSIONS OF MANGANESE CARBONYL HALIDE SPECIES BY ULTRAVIOLET SPECTROSCOPY [J].

BAMFORD, CH ;

BURLEY, JW ;

COLDBECK, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (17) :1846-&

[5] KINETICS OF EXCHANGE OF C-13 MONOXIDE WITH MANGANESE PENTACARBONYL BROMIDE [J].

BERRY, A ;

BROWN, TL .

INORGANIC CHEMISTRY, 1972, 11 (06) :1165-&

[6] ELECTRONIC SPECTRA OF SOME PENTACARBONYL COMPOUNDS OF MANGANESE AND RHENIUM [J].

BLAKNEY, GB ;

ALLEN, WF .

INORGANIC CHEMISTRY, 1971, 10 (12) :2763-&

[7]

BRYAN RF, 1969, ABSTRACTS AM CRYSTAL, pM6

[8] PHOTOLYSIS AND SPECTROSCOPY WITH POLARIZED-LIGHT - KEY TO PHOTOCHEMISTRY OF CR(CO)5 AND RELATED SPECIES [J].

BURDETT, JK ;

GRZYBOWSKI, JM ;

PERUTZ, RN ;

POLIAKOFF, M ;

TURNER, JJ ;

TURNER, RF .

INORGANIC CHEMISTRY, 1978, 17 (01) :147-154

[9] THEORETICAL ASPECTS OF THE PHOTOCHEMISTRY OF ORGANOMETALLICS .3. POTENTIAL-ENERGY CURVES FOR THE PHOTODISSOCIATION OF FE(CO)5 [J].

DANIEL, C ;

BENARD, M ;

DEDIEU, A ;

WIEST, R ;

VEILLARD, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1984, 88 (21) :4805-4811

[10]

DANIEL C, 1986, NEW J CHEM, V10, P83

← 1 2 3 4 →