ROTATING FRAME SPIN-LATTICE RELAXATION IN THE PRESENCE OF AN OFF-RESONANCE RADIOFREQUENCY FIELD - SCALAR RELAXATION OF P-31 IN PBR3

被引：19
作者：
JAMES, TL
MATSON, GB
机构：
[1] Department of Pharmaceutical Chemistry, University of California, San Francisco
来源：
JOURNAL OF MAGNETIC RESONANCE | 1979年 / 33卷 / 02期
基金：
美国国家科学基金会; 美国国家卫生研究院;
关键词：
D O I：
10.1016/0022-2364(79)90253-1
中图分类号：
Q5 [生物化学];
学科分类号：
071010 ; 081704 ;
摘要：
An NMR technique involving study of spin-lattice relaxation in the presence of an off-resonance radiofrequency field (Tiff) which can be conveniently performed on commercial Fourier transform NMR spectrometers is described. Applicability of the technique for investigation of scalar relaxation of the second kind is illustrated for 31P in phosphorus tribromide which is relaxed via scalar coupling to the quadrupolar bromine nucleus. The normal on-resonance TI, was calculated for 31P from the Ti; results and was found to be 0.13 sec., in agreement with published values. © 1979.
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页码：345 / 353
页数：9
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