EFFECT OF CHAIN-LENGTH ON THE RATE OF QUATERNIZATION OF ALKYL AMINES

被引：5
作者：
FRIEDLI, FE
机构：
[1] Sherex Chemical Co., Inc., Dublin, 43O17, OH
来源：
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY | 1990年 / 67卷 / 07期
关键词：
D O I：
10.1007/BF02638964
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Trialkyl amines from triethyl to tristearylamine were quaternized with benzyl chloride and compared for the effect of chain length on the rate of quaternization. Triethylamine reacted about twice as fast as tripropylamine with virtually no chain-length effect from propyl to stearyl. Results are compared to previous rate studies on steric hindrance and chain-length dependence. © 1990 American Oil Chemists' Society.
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页码：469 / 471
页数：3
相关论文
共 33 条
[1]  
ALBERTI G, 1980, ANN CHIM-ROME, V70, P167
[2]  
ALDER RW, 1971, MECH ORGANIC CHEM, P40
[3]   CELLULAR INTERRELATIONSHIPS DURING INVITRO GRANULOPOIESIS [J].
ALLEN, TD ;
DEXTER, TM .
DIFFERENTIATION, 1976, 6 (03) :191-194
[4]  
ANDREEV VP, 1979, ZH ORG KHIM+, V15, P464
[5]   STERIC ENHANCEMENT OF RESONANCE [J].
BALIAH, V ;
KANAGASABAPATHY, VM .
TETRAHEDRON, 1978, 34 (24) :3611-3615
[6]   INFLUENCE OF STEREOCHEMISTRY ON PKA, RATE OF QUATERNIZATION AND PARTITION COEFFICIENTS OF CORYNANTHEIDINE-TYPE ALKALOIDS [J].
BECKETT, AH ;
DWUMABAD.D .
JOURNAL OF PHARMACY AND PHARMACOLOGY, 1969, S 21 :S162-&
[7]   QUATERNIZATION AT AN SP2 NITROGEN .2. ANALYSIS ON THE SUBSTITUENT EFFECT AND ON THE NATURE OF THE TRANSITION-STATE [J].
BEHERA, GB ;
SHARMA, A .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1979, 52 (02) :604-607
[8]   EXPERIMENTAL-EVIDENCE FOR GEOMETRICAL VARIATIONS IN TRANSITION-STATE OF SN2 REACTION [J].
BERG, U ;
GALLO, R ;
METZGER, J ;
CHANON, M .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (05) :1260-1262
[9]   STERIC EFFECTS IN SN2 REACTIONS - DETERMINATION OF TRANSITION-STATE STRUCTURES FOR THE QUATERNIZATION OF 2-ALKYLPYRIDINES AND 2-ALKYLTHIAZOLES BY A COMBINED EXPERIMENTAL AND MOLECULAR MECHANICS PROCEDURE [J].
BERG, U ;
GALLO, R .
ACTA CHEMICA SCANDINAVICA SERIES B-ORGANIC CHEMISTRY AND BIOCHEMISTRY, 1983, 37 (08) :661-673
[10]  
BERG U, 1980, J CHEM SOC P2, V9, P1350
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