NONPLANAR BIS(1,3-DITHIOLE) DONORS AFFORDING NOVEL CATION-RADICAL SALTS

被引：25

作者：

YAMASHITA, Y ^{[1
]}

ONO, K ^{[1
]}

TANAKA, S ^{[1
]}

IMAEDA, K ^{[1
]}

INOKUCHI, H ^{[1
]}

机构：

[1] GRAD UNIV ADV STUDIES,DEPT STRUCT MOLEC SCI,OKAZAKI 444,JAPAN

来源：

ADVANCED MATERIALS | 1994年 / 6卷 / 04期

关键词：

D O I：

10.1002/adma.19940060408

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A nonplanar molecule that forms stable ion radical salts is reported, demonstrating that planar molecules are not a prerequisite for the preparation of organic conductors. The results of cyclic voltammetry and X‐ray structural analysis are presented for stable single crystals of the cation radical salt of the dibenzo derivative of 4,9‐bis(1,3,‐dithio‐2‐ylidene)‐4,9‐dihydronaphtho[2,3‐c][1,2,5]thiadiazole. This is the first stable cation radical salt to have been succesfully obtained from a nonplanar molecule. Copyright © 1994 Verlag GmbH & Co. KGaA, Weinheim

引用

页码：295 / 297

页数：3

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