A NEW P-31 NMR METHOD FOR THE ENANTIOMERIC EXCESS DETERMINATION OF DIOLS AND SECONDARY DIAMINES WITH C-2 SYMMETRY

被引：21

作者：

BRUNEL, JM ^{[1
]}

FAURE, B ^{[1
]}

机构：

[1] UNIV AIX MARSEILLE 1,CHIM COORDINAT LAB,F-13397 MARSEILLE,FRANCE

来源：

TETRAHEDRON-ASYMMETRY | 1995年 / 6卷 / 09期

关键词：

D O I：

10.1016/0957-4166(95)00311-C

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new reagent for the determination of enantiomeric excess of chiral diols and diamines with C-2 symmetry is described. This derivatizing agent easily prepared from PCl3 and (1R,2S,5R)-(-)menthol allows an accurate analysis of the diastereomeric derivatives by P-31 NMR spectroscopy.

引用

页码：2353 / 2356

页数：4

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