REACTIVITY PATTERNS OF H-2 AND CO WITH A RHODIUM(II) SALEN DERIVATIVE - FORMATION OF HYDRIDE, FORMYL, AND DIMETAL KETONE COMPLEXES AND RHODIUM REDUCTION

被引：23

作者：

BUNN, AG ^{[1
]}

WEI, ML ^{[1
]}

WAYLAND, BB ^{[1
]}

机构：

[1] UNIV PENN,DEPT CHEM,PHILADELPHIA,PA 19104

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 09期

关键词：

D O I：

10.1021/om00021a006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A benzene soluble dimeric rhodium(II) salen derivative, [(ttbs)Rh](2), with a weak Rh-Rh bond (13 kcal mol(-1)) reacts with H-2 and CO to produce hydride, metalloketone, and formyl complexes, but reaction. of (ttbs)Rh-H with CO also induces migration. of H+ from rhodium to the salen ligand to form a rhodium(I) dicarbonyl complex, (Httbs)Rh(CO)(2).

引用

页码：3390 / 3392

页数：3

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