TIME-RESOLVED RAMAN MEASUREMENTS IN ALPHA-QUARTZ SHOCKED TO 60 KBAR

被引:20
作者
GUSTAVSEN, RL [1 ]
GUPTA, YM [1 ]
机构
[1] WASHINGTON STATE UNIV,DEPT PHYS,SHOCK DYNAM LAB,PULLMAN,WA 99164
关键词
D O I
10.1063/1.356176
中图分类号
O59 [应用物理学];
学科分类号
摘要
An experimental method for obtaining time resolved Raman spectra in shock wave experiments is described. A key aspect of this method is the use of optical fibers to transmit light from a pulsed laser to the sample and to transmit the scattered light to the recording equipment. Using this method we have measured changes in the A1(466 cm-1) Raman line of alpha-quartz shocked along the z axis to 60 kbar. For the same density compression, the line shifts under shock loading are considerably larger than under hydrostatic loading. Because shifts of the A1(466 cm-1) line in quartz are correlated with changes in the Si-O-Si bond angle, which, in turn, is the primary compression mechanism in quartz, the present results indicate the role of nonhydrostatic stresses on compression at the molecular level.
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页码:2837 / 2844
页数:8
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