AN EASY APPROACH TO 1-SILYLATED KETONES AND ASYMMETRICAL 1,6-DICARBONYL AND 1,8-DICARBONYL COMPOUNDS

被引：6
作者：
FIANDANESE, V
PUNZI, A
RAVASIO, N
机构：
[1] Centro CNR di Studio sulle Metodollogie Innovative, Sintesi Organiche Dipartimento di Chimica, Università di Bari, 70126 Bati
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 447卷 / 02期
关键词：
D O I：
10.1016/0022-328X(93)80255-A
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A variety of 1-silylated ketones and asymmetrical 1,6- and 1,8-dicarbonyl compounds are synthesized with 70-85% yields by means of Pd-catalysed selective hydrogenation reactions of the corresponding unsaturated conjugated products, readily available by a previously reported procedure.
引用
收藏
页码：311 / 315
页数：5
相关论文
共 35 条
[31]  
SHOSTAKOVSKII MF, Patent No. 233912
[32]   ORGANOSILICON CHEMISTRY .33. ALIPHATIC ORGANO-FUNCTIONAL SILOXANES [J].
SOMMER, LH ;
PIOCH, RP ;
MARANS, NS ;
GOLDBERG, GM ;
ROCKETT, J ;
KERLIN, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1953, 75 (12) :2932-2934
[33]  
SOMMER LH, Patent No. 1460166
[34]   ALUMINUM ALKYLS WITH HETEROATOMS .10. ELECTRON-IMPACT FRAGMENTATION OF TRIMETHYLSILYLALKANONES [J].
SONNEK, G ;
BAUMGARTEN, KG ;
HABISCH, D .
JOURNAL FUR PRAKTISCHE CHEMIE, 1980, 322 (01) :94-98
[35]  
SOUSSAN G, 1972, B SOC CHIM FR, P4233
1234