INTERCALATION AND BILAYER FORMATION OF PHOSPHOLIPIDS IN GAMMA-TYPE LAYERED TRANSITION-METAL PHOSPHATES

被引：14

作者：

KANZAKI, Y ^{[1
]}

ABE, M ^{[1
]}

机构：

[1] SHOWA COLL PHARMACEUT SCI, MACHIDA, TOKYO 194, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1992年 / 65卷 / 01期

关键词：

D O I：

10.1246/bcsj.65.180

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Intercalation of natural phospholipids, phosphatidylethanolamine (PEA) and phosphatidylcholine (PC), into inorganic layered compounds was examined in ethanol and chloroform solutions. Gamma-Type titanium(IV) phosphate and zirconium(IV) phosphate were selected as host layered compounds. They are strong solid acids and also known as inorganic ion exchangers. The intercalation of PEA was propagated in chloroform solution in the presence of n-alkylamine forming a bilayers of PEA-alkylamine mixture. The direct reaction of PEA with gamma-phosphates was not successful. On the other hand PC reacted directly with the layered compounds either in the chloroform or in the ethanol solution of PC and successfully formed bilayers.

引用

收藏

页码：180 / 185

页数：6

相关论文

共 17 条

[1] CRYSTALLINE INSOLUBLE ACID SALTS OF TETRAVALENT METALS .28. SYNTHESIS OF CRYSTALLINE TI(HPO4)2.2H2O BY THE HF PROCEDURE AND SOME COMMENTS ON ITS FORMATION AND STRUCTURE [J].

ALBERTI, G ;

COSTANTINO, U ;

GIOVAGNOTTI, MLL .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1979, 41 (05) :643-647

[2] PREPARATION AND ION-EXCHANGE PROPERTIES OF A NEW PHASE OF CRYSTALLINE TITANIUM PHOSPHATE, TI(HPO4)2.2H2O [J].

ALLULLI, S ;

FERRAGINA, C ;

LAGINESTRA, A ;

MASSUCCI, MA ;

TOMASSINI, N .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1977, 39 (06) :1043-1048

[3] NEW CRYSTALLINE PHASES OF ZIRCONIUM PHOSPHATE POSSESSING ION-EXCHANGE PROPERTIES [J].

CLEARFIELD, A ;

BLESSING, RH ;

STYNES, JA .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1968, 30 (08) :2249-+

[4]

Clearfield A, 1982, INORGANIC ION EXCHAN, P1

[5] INTERCALATION OF ALKANOLS AND ALKYLAMINES IN INSOLUBLE ACID SALTS OF TETRAVALENT METALS HAVING A LAYERED STRUCTURE OF GAMMA-TYPE [J].

COSTANTINO, U .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1981, 43 (08) :1895-1902

[6] INTERCALATION OF ALKANOLS AND GLYCOLS INTO ZIRCONIUM(IV) HYDROGEN-PHOSPHATE MONOHYDRATE [J].

COSTANTINO, U .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1979, (02) :402-405

[7] THE INTERCALATION OF NORMAL-ALKYLAMINES INTO LAYERED TRANSITION-METAL PHOSPHATES-SOLVENT EFFECT [J].

KANZAKI, Y ;

ABE, M .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1991, 64 (06) :1846-1853

[8] STUDIES OF INORGANIC-ION EXCHANGERS .6. THE FORMATION REGION AND DEHYDRATION BEHAVIOR OF VARIOUS TITANIUM(IV) BIS(HYDROGENORTHOPHOSPHATE) HYDRATES [J].

KOBAYASHI, E ;

YAMAZAKI, S .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1983, 56 (06) :1632-1636

[9] SYNTHESIS AND ION-EXCHANGE PROPERTIES OF TIH2(PO4)2.1/2H2O [J].

KOBAYASHI, E .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1975, 48 (11) :3114-3119

[10] INORGANIC LAYER COMPOUNDS - PHENOMENA OF INTERFACE REACTIONS WITH ORGANIC-COMPOUNDS [J].

LAGALY, G .

NATURWISSENSCHAFTEN, 1981, 68 (02) :82-88