HYDRORUTHENATION OF PROP-2-YNYLTRIPHENYLPHOSPHONIUM BROMIDE - SYNTHESIS, CRYSTAL-STRUCTURE AND REACTIONS OF [RUBR(CH=CHCH(2)PPH(3))(CO)(PPH(3))(2)]PF6

被引：16

作者：

ALCOCK, NW

CARTWRIGHT, J

HILL, AF

MARCELLIN, M

RAWLES, HM

机构：

[1] UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,LONDON SW7 2AY,ENGLAND

[2] UNIV WARWICK,DEPT CHEM,COVENTRY CV4 7AL,W MIDLANDS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 03期

关键词：

D O I：

10.1039/c39950000369

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of the complex [RuClH(CO)(PPh(3))(3)] with prop-2-ynyltriphenylphosphonium bromide ([Ph(3)PCH(2)C equivalent to CH]Br) followed by NH4PF6 provides the crystallographically characterised salt [RuBr(CH=CHCH(2)PPh(3))(CO)(PPh(3))(2)]PF6 which by virtue of the coordinative unsaturation at the ruthenium centre undergoes addition of the ligands CNC(6)H(3)Me(2)-2,6, and CO to Ru and insertion of SO2 into the Ru-C sigma-bond.

引用

页码：369 / 370

页数：2

共 5 条

[1] RUTHENATETRABORANES - SYNTHESIS OF [RU(B3H8)(PPH3)(HB(PZ)3)] AND CRYSTAL-STRUCTURE OF [RUCL(PPH3)2(HB(PZ)3)] (PZ = PYRAZOL-1-YL) [J].