USE OF A GUANIDINIUM IONOPHORE IN A HYDROGEN SULFITE-SELECTIVE ELECTRODE

被引：45
作者：
HUTCHINS, RS
MOLINA, P
ALAJARIN, M
VIDAL, A
BACHAS, LG
机构：
[1] UNIV KENTUCKY,DEPT CHEM,LEXINGTON,KY 40506
[2] UNIV KENTUCKY,CTR MEMBRANE SCI,LEXINGTON,KY 40506
[3] UNIV MURCIA,FAC QUIM,DEPT QUIM ORGAN,E-30071 MURCIA,SPAIN
来源：
ANALYTICAL CHEMISTRY | 1994年 / 66卷 / 19期
关键词：
D O I：
10.1021/ac00091a030
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
A liquid membrane-based anion-selective electrode for hydrogen sulfite has been developed using a guanidinium ionophore in a poly(vinyl chloride) membrane. At pH 6.00, a logarithmic response to hydrogen sulfite in the range 5.0 x 10(-5) to 0.500 M is observed with a detection limit of 3.9 (+/-0.3) x 10(-5) M (n = 6). The electrode demonstrated minimal response to other anions, with perchlorate (K-HSO3-,ClO4-(pot) = 7.0 X 10(-3)) and salicylate (K-HSO3-,salicylate(pot) = 4.6 X 10(-3)) being the two strongest interferents. H-1-NMR complexation was used to study the interaction between hydrogen sulfite and the ionophore in this novel HSO3- sensor.
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页码：3188 / 3192
页数：5
相关论文
共 43 条
[1]   ANION SELECTIVITY OF METALLOPORPHYRINS IN MEMBRANES [J].
AMMANN, D ;
HUSER, M ;
KRAUTLER, B ;
RUSTERHOLZ, B ;
SCHULTHESS, P ;
LINDEMANN, B ;
HALDER, E ;
SIMON, W .
HELVETICA CHIMICA ACTA, 1986, 69 (04) :849-854
[2]  
[Anonymous], 1975, PURE APPL CHEM, V48, P129
[3]   SALICYLATE-SELECTIVE MEMBRANE-ELECTRODE BASED ON TIN(IV) TETRAPHENYLPORPHYRIN [J].
CHANIOTAKIS, NA ;
PARK, SB ;
MEYERHOFF, ME .
ANALYTICAL CHEMISTRY, 1989, 61 (06) :566-570
[4]   POTENTIOMETRIC PHOSPHATE SELECTIVE ELECTRODE BASED ON A MULTIDENDATE TIN(IV) CARRIER [J].
CHANIOTAKIS, NA ;
JURKSCHAT, K ;
RUHLEMANN, A .
ANALYTICA CHIMICA ACTA, 1993, 282 (02) :345-352
[5]  
CHANIOTAKIS NA, 1988, ANAL CHEM, V60, P188
[6]  
Daunert S, 1989, Prog Clin Biol Res, V292, P215
[7]   ANION-SELECTIVE ELECTRODES BASED ON A HYDROPHOBIC VITAMIN-B12 DERIVATIVE [J].
DAUNERT, S ;
BACHAS, LG .
ANALYTICAL CHEMISTRY, 1989, 61 (05) :499-503
[8]   ION-SELECTIVE ELECTRODES USING AN IONOPHORE COVALENTLY ATTACHED TO CARBOXYLATED POLY(VINYL CHLORIDE) [J].
DAUNERT, S ;
BACHAS, LG .
ANALYTICAL CHEMISTRY, 1990, 62 (14) :1428-1431
[9]   HUMAN PLACENTAL STERYLSULFATASE - INTERACTION OF THE ISOLATED ENZYME WITH SUBSTRATES, PRODUCTS, TRANSITION-STATE ANALOGS, AMINO-ACID MODIFIERS AND ANION TRANSPORT INHIBITORS [J].
DIBBELT, L ;
KUSS, E .
BIOLOGICAL CHEMISTRY HOPPE-SEYLER, 1991, 372 (03) :173-185
[10]   ANION RECEPTOR MOLECULES - SYNTHESIS AND SOME ANION BINDING PROPERTIES OF MACROCYCLIC GUANIDINIUM SALTS [J].
DIETRICH, B ;
FYLES, TM ;
LEHN, JM ;
PEASE, LG ;
FYLES, DL .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1978, (21) :934-936
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