SYNTHESES AND REACTIONS OF METAL ORGANICS .14. SYNTHESES OF FLUOROALKYL SILICATES

被引：4
作者：
YOSHINO, N
TERAJIMA, H
HIRAI, H
机构：
[1] Department of Industrial Chemistry, Faculty of Engineering, , Science University of Tokyo, 162 Shinjuku-ku, Tokyo, Kagurazaka
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1990年 / 20卷 / 06期
关键词：
D O I：
10.1080/00945719008048169
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The new compounds, tetrakis(1H,1H,3H-perfluoropropyl) silicate, Si(OCH2CF2CF2H)4, tetrakis(1H,1H,5H-perfluoropentyl) silicate, Si[OCH2(CF2CF2)2H]4, tetrakis(1H,1H,7H-perfluoroheptyl) silicate, Si[OCH2(CF2CF2)3H]4 and tetrakis-(1H,1H,9H-perfluorononyl) silicate, Si[OCH2(CF2 CF2)4 H34, were prepared by the reaction of silicon tetrachloride with fluoro-substituted alcohols in the presence of ammonia. The 1H, 13C, 19F NMR and IR spectral data of these silicates were obtained. © 1990, Taylor & Francis Group, LLC. All rights reserved.
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页码：729 / 741
页数：13
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