STERICALLY HINDERED ORGANOTIN COMPOUNDS .3. THE REACTION BETWEEN DI-TERT-BUTYLTIN OXIDE AND ORGANOBORONIC ACIDS

被引：30

作者：

BROWN, P ^{[1
]}

MAHON, MF ^{[1
]}

MOLLOY, KC ^{[1
]}

机构：

[1] UNIV BATH, SCH CHEM, BATH BA2 7AY, AVON, ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 24期

关键词：

D O I：

10.1039/dt9920003503

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between (But2SnO)3 and BR(OH), [R = Ph or 2,4,6-Me3C6H2 (mes)] has been investigated and found to yield two classes of product. The first is a boron-rich species, cyclo-But2SnO(RBO)2, which exists alongside its acyclic hydrolysis product SnBut2[OB(OH)R]2. The second product, which is tin-rich, SnBut2(OH)2[(But2SnO)2OBR]2, can be formulated as cyclo-RBO(But2SnO)2 chelated across one Sn-O-Sn unit by a molecule of SnBut2(OH)2. The crystal and molecular structures of SnBut2[OB(OH)Ph]2 and SnBut2(OH)2[(But2SnO)2OBC6H2Me3-2,4,6]2.2MeCN have been determined.

引用

页码：3503 / 3509

页数：7

共 37 条

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