SYNTHESES, PROPERTIES, AND CRYSTAL AND MOLECULAR-STRUCTURES OF BROMO[N,N-BIS(2-HYDROXYETHYL)GLYCINATO]COPPER(II) AND AQUABROMO[N,N-BIS(2-HYDROXYETHYL)GLYCINATO]COPPER(II)

被引：13

作者：

YAMAGUCHI, H ^{[1
]}

INOMATA, Y ^{[1
]}

TAKEUCHI, T ^{[1
]}

机构：

[1] SOPHIA UNIV,FAC SCI & TECHNOL,DEPT NAT SCI,7-1 KIOICHO,CHIYODA KU,TOKYO 102,JAPAN

来源：

INORGANICA CHIMICA ACTA | 1991年 / 181卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)85256-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The syntheses and characterization of bromo[N,N-bis(2-hydroxyethyl)glycinato]copper(II) (1) and aquabromo[N,N-bis(2-hydroxyethyl)glycinato]copper(II) (2) are presented. X-ray crystal structure determinations of both complexes have been carried out. Complex 1 crystallizes in the monoclinic system, space group P21/n, with Z = 4 and unit cell parameters a = 12.910(2), b = 8.478(1) and c = 8.894(2) angstrom, and beta = 105.11(1)-degrees. Complex 2 crystallizes in the orthorhombic system, space group P2(1)2(1)2(1), with Z = 4 and unit cell parameters a = 8.7672(9), b = 15.594(3) and c = 7.4996(5) angstrom. In complex 1 the copper atom is in a trigonal bipyramidal geometry, while complex 2 has a distorted octahedral configuration.

引用

页码：31 / 36

页数：6

共 8 条

[1] N,N-BIS(2-HYDROXYETHYL)GLYCINE [J].

CODY, V ;

HAZEL, J ;

LANGS, D .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1977, 33 (MAR15) :905-907

[2] BIVALENT-METAL COMPLEXES OF N,N-BIS(2-HYDROXYETHYL)GLYCINE [J].

INOMATA, Y ;

TAKEUCHI, T ;

MORIWAKI, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1976, 49 (06) :1568-1572

[3]

Nakatani K., 1986, IEEE International Conference on Computer-Aided Design: ICCAD-86. A Conference for the EE CAD Professional. Digest of Technical Papers (Cat. No.86CH2353-1), P324

[4]

SAKURAI T, 1986, OYO BUTSURIGAKU SENS, P144

[5]

SAKURAI T, 1967, REP I PHYS CHEM RES, V43, P62

[6] SYNTHESIS, PROPERTIES AND CRYSTAL AND MOLECULAR-STRUCTURE OF ISOTHIOCYANATO[N,N-BIS(2-HYDROXYETHYL)GLYCINATO]COPPER(II) MONOHYDRATE [J].

YAMAGUCHI, H ;

INOMATA, Y ;

TAKEUCHI, T .

INORGANICA CHIMICA ACTA, 1990, 172 (01) :105-108

[7] SYNTHESIS, PROPERTIES, AND CRYSTAL AND MOLECULAR-STRUCTURE OF CHLORO[N,N-BIS(2-HYDROXYETHYL)GLYCINATO]COPPER(II) [J].

YAMAGUCHI, H ;

NAGASE, M ;

YUKAWA, Y ;

INOMATA, Y ;

TAKEUCHI, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1988, 61 (08) :2763-2766

[8] SYNTHESIS, PROPERTIES, AND CRYSTAL AND MOLECULAR-STRUCTURE OF N,N-BIS(2-HYDROXYETHYL)GLYCINATO COPPER(II) PERCHLORATE MONOHYDRATE [J].

YAMAGUCHI, H ;

INOMATA, Y ;

TAKEUCHI, T .

INORGANICA CHIMICA ACTA, 1989, 161 (02) :217-221

← 1 →