NITRIC-ACID REACTION OF CYCLOHEXANOL TO ADIPIC ACID

被引：44
作者：
CASTELLAN, A [1 ]
BART, JCJ [1 ]
CAVALLARO, S [1 ]
机构：
[1] UNIV MESSINA,DIPARTIMENTO CHIM IND,I-98010 ST AGATA,ITALY
来源：
CATALYSIS TODAY | 1991年 / 9卷 / 03期
关键词：
D O I：
10.1016/0920-5861(91)80050-J
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The reaction chemistry of the oxidation of cyclohexanol to adipic acid under the influence of nitric acid has been critically reviewed. With the traditional process maximum selectivity towards adipic acid is reached at a high degree of HNO3 consumption. Only under particular reaction conditions can the nitric acid consumption be reduced without affecting the selectivity; certain conditions even lead to improved selectivity.
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页码：255 / 283
页数：29
相关论文
共 64 条
[1]  
BORSARI A, 1979, CHEM IND-LONDON, P524
[2]   SYNTHESIS OF ADIPIC ACID VIA THE NITRIC-ACID OXIDATION OF CYCLOHEXANOL IN A 2-STEP BATCH PROCESS [J].
CASTELLAN, A ;
BART, JCJ ;
CAVALLARO, S .
CATALYSIS TODAY, 1991, 9 (03) :285-299
[3]   SYNTHESIS OF ADIPIC ACID VIA NITRIC-ACID OXIDATION OF CYCLOHEXANOL IN A 2-STEP CONTINUOUS PROCESS [J].
CASTELLAN, A ;
BART, JCJ ;
CAVALLARO, S .
CATALYSIS TODAY, 1991, 9 (03) :301-322
[4]  
CASTELLAN A, 1986, Patent No. 41003
[5]  
Danly D. E., 1978, KIRKOTHMER ENCY CHEM, V1, P510
[6]   KINETICS OF NITROUS GAS ABSORPTION IN AQUEOUS NITRIC ACID [J].
DENBIGH, KG ;
PRINCE, AJ .
JOURNAL OF THE CHEMICAL SOCIETY, 1947, (JUN) :790-801
[7]  
Deno N. C., 1976, ACS SYM SER, V22, P156
[8]  
DZHAPARIDZE AV, 1973, SOOBSHCH AKAD NAUK G, V71, P369
[9]   ALKYL NITRATION OF ACTIVE METHYLENE COMPUNDS .4. MONONITRATION OF KETONES [J].
FEUER, H ;
PIVAWER, PM .
JOURNAL OF ORGANIC CHEMISTRY, 1966, 31 (10) :3152-&
[10]  
FISCHER RH, 1980, SYNTHESIS-STUTTGART, P261
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