The calculation of rate constant of electron transfer reaction at electrodes

被引:0
|
作者
Wu, YS [1 ]
Zhou, ZY [1 ]
Fu, AP [1 ]
机构
[1] Qufu Normal Univ, Dept Chem, Qufu 273165, Peoples R China
关键词
D O I
暂无
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
After the electron transfers from the metal electrode to the Fe3+(H2O)(6) ion, the free energy of activation of this electron transfer reaction is calculated, then using the transition probability which is calculated by the perturbed degeneration theory and the Fermi golden rule,, the rate constant is gotten. Compared with the experimental results, it is satisfactory.
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页码:59 / 62
页数:4
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