[TERT-BUTYLCYANIDE.LITHIUM BIS(TRIMETHYLSILYL)-AMIDE]2, A MODEL OF THE INTERMEDIATE RCN.MR' COMPLEX FORMED IN REACTIONS OF CYANIDES RCN WITH ORGANOMETALLIC COMPOUNDS R'M

被引：35
作者：
BOCHE, G
LANGLOTZ, I
MARSCH, M
HARMS, K
FRENKING, G
机构：
[1] Fachbereich Chemie, Universität Marburg
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 08期
关键词：
D O I：
10.1002/anie.199311711
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The dialkylation and dideuteration of cyanides are proposed to proceed through intermediates of the type RR'CHCN.LiR''. The title compound 1 (central framework shown on the right) is the first structurally characterized compound of this type. The results of ab initio calculations on the model compound H3CCN.LiNH2 are in agreement with the high stability and the energetically favorable intramolecular proton shift found experimentally.
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页码：1171 / 1173
页数：3
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