MADE-TO-ORDER CONTROL OF THE DIRECTION OF ELECTRONIC-ENERGY TRANSFER IN TETRANUCLEAR LUMINESCENT METAL-COMPLEXES

被引：51

作者：

DENTI, G

SERRONI, S

CAMPAGNA, S

RICEVUTO, V

BALZANI, V

机构：

[1] UNIV MESSINA,DIPARTIMENTO CHIM INORGAN & STRUTTURA MOLEC,I-98100 MESSINA,ITALY

[2] UNIV BOLOGNA,DIPARTIMENTO CHIM G CIAMICIAN,I-40126 BOLOGNA,ITALY

来源：

COORDINATION CHEMISTRY REVIEWS | 1991年 / 111卷

关键词：

D O I：

10.1016/0010-8545(91)84028-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We have synthesized the tetranuclear complexes Ru[(mu-2,3-dpp)Ru(bpy)2]2[(mu-2,3-dpp)Ru(biq)2]8+ and Ru[(mu-2,3-dpp)Ru(bpy)2]2[(mu-2,3-dpp)Os(bpy)2]8+ which belong to the M[(BL)M(L)2]3(8+) family (M = Ru2+ or Os2+; BL = 2,3-dpp or 2,5-dpp; L = bpy or biq; dpp = bis(2-pyridyl)pyrazine; bpy = 2,2'-bipyridine; biq = 2,2'-biquinoline). Luminescence investigations show that in the complexes of this family the electronic energy originated upon light absorption can be channelled in any desired direction along the supramolecular structure by a suitable choice of M, L, and BL.

引用

页码：227 / 236

页数：10

共 18 条

[1] DESIGN OF ANTENNA-SENSITIZER POLYNUCLEAR COMPLEXES - SENSITIZATION OF TITANIUM-DIOXIDE WITH [RU(BPY)2(CN)2]2RU(BPY(COO)2)22- [J].