FLUORESCENT PHOTOINDUCED ELECTRON-TRANSFER SENSORS - THE SIMPLE LOGIC AND ITS EXTENSIONS

被引：0
作者：
BISSELL, RA
DE SILVA, AP
GUNARATNE, HQN
LYNCH, PLM
MCCOY, CP
MAGUIRE, GEM
SANDANAYAKE, KRAS
机构：
来源：
FLUORESCENT CHEMOSENSORS FOR ION AND MOLECULE RECOGNITION | 1993年 / 538卷
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中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
The principle of photoinduced electron transfer is combined with the modular system 'Fluorophore-Spacer-Receptor' to develop the phenomenon of cation-responsive fluorescence. pH controlled 'on-off' fluorescence is demonstrated in the case of the dialkylaminoalkyl heterocyclic derivative 1a. The modular system is then extended in two directions. In the first of these, targetting/anchoring modules are added to allow the investigation of proton fields in microheterogeneous membrane media with high spatial resolution. The sensor family 2a-f is the realization of this approach. The second direction employs phosphorescent (instead of fluorescent) modules with/without protective shields to permit the development of phosphorescent pH sensing in an interference-free manner within intrinsically fluorescent environments. Sensors like 3 in aqueous beta-cyclodextrin solution illustrate the possibilities of this idea.
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页码：45 / 58
页数：14
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[41]   PHOTOINDUCED ELECTRON-TRANSFER IN ORGANIZED ASSEMBLIES [J].
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