ENTHALPIES OF FORMATION OF SILANES

被引：18

作者：

DAVIDSON, IMT

机构：

[1] Department of Chemistry, The University, Leicester

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 170卷 / 03期

关键词：

D O I：

10.1016/S0022-328X(00)92073-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Benson's electrostatic model for calculating enthalpies of formation has been applied to the methylsilanes and some disilanes, conforming recent conclusions from electron-impact measurements that these silanes essentially follow bond additivity rules, with very small interaction corrections. These findings are shown to be consistent with recently measured bond dissociation energies. © 1979.

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页码：365 / 372

页数：8

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DAVIDSON IMT, UNPUBLISHED