CONVENIENT SYNTHESES OF OPTICALLY-ACTIVE ABSCISIC-ACID AND XANTHOXIN

被引：11

作者：

SAKAI, K

TAKAHASHI, K

NUKANO, T

机构：

[1] Sagami Chemical Research Center, Sagamihara, Kanagawa, 229

来源：

TETRAHEDRON | 1992年 / 48卷 / 38期

关键词：

D O I：

10.1016/S0040-4020(01)80491-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Reformatsky reaction of 3-(bromomethyl)crotonate with an optically active epoxycyclohexane aldehyde derivative (3), followed by dehydration, gave the chiral dienoic acid (6)stereospecifically. The product was derived to optically active abscisic acid (1) and xanthoxin (2) successfully.

引用

页码：8229 / 8238

页数：10

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