POLYMER ELECTROLYTE COMPLEXES OF LICLO4 AND COMB POLYMERS OF SILOXANE WITH OLIGO-OXYETHYLENE SIDE-CHAINS

被引：105

作者：

FISH, D ^{[1
]}

KHAN, IM ^{[1
]}

WU, E ^{[1
]}

SMID, J ^{[1
]}

机构：

[1] SUNY COLL ENVIRONM SCI & FORESTRY,COLL ENVIRONM SCI & FORESTRY,POLYMER RES INST,DEPT CHEM,SYRACUSE,NY 13210

来源：

BRITISH POLYMER JOURNAL | 1988年 / 20卷 / 03期

关键词：

Lithium compounds - Polymers;

D O I：

10.1002/pi.4980200320

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Polysiloxanes with oligo-oxyethylene side chains were synthesized from poly(hydrogenmethylsiloxane) and characterized by **1H n. m. r. , **2**9Si n. m. r. , i. r. and g. p. c. Cyclic analogues were used as model compounds and synthesized from tetramethylcyclotetrasiloxane. Polymer electrolyte complexes were made from the comb polymers and LiClO//4 by solvent-casting from THF, and their conductivities measured as a function of temperature and studied by differential scanning calorimetry and correlated with their conductivity behaviour.

引用

页码：281 / 288

页数：8

共 22 条

[1]

Armand M. B., 1979, Fast Ion Transport in Solids. Electrodes and Electrolytes, P131

[2]

BALL SE, 1986, J POLYM SCI PL, V24, P165

[3] IONIC CONDUCTIVITIES OF POLY(METHOXY POLYETHYLENE-GLYCOL MONOMETHACRYLATE) COMPLEXES WITH LISO3CH3 [J].

BANNISTER, DJ ;

DAVIES, GR ;

WARD, IM ;

MCINTYRE, JE .

POLYMER, 1984, 25 (11) :1600-1602

[4]

BLONSKY PM, 1984, J AM CHEM SOC, V106, P6854, DOI 10.1021/ja00334a071

[5] POLY(DIMETHYLSILOXANE)-POLY(ETHYLENE OXIDE) BASED POLYURETHANE NETWORKS USED AS ELECTROLYTES IN LITHIUM ELECTROCHEMICAL SOLID-STATE BATTERIES [J].

BOURIDAH, A ;

DALARD, F ;

DEROO, D ;

CHERADAME, H ;

LENEST, JF .

SOLID STATE IONICS, 1985, 15 (03) :233-240

[6] IONIC-CONDUCTIVITY IN POLY(D-POLY(PROPYLENE GLYCOL) ITACONATE) SALT MIXTURES [J].

COWIE, JMG ;

MARTIN, ACS .

POLYMER, 1987, 28 (04) :627-632

[7]

COWIE JMG, 1987, POLYM COMMUN, V28, P120

[8]

FISH D, 1986, MAKROMOL CHEM-RAPID, V7, P115

[9]

FISH D, 1985, MAKROMOL CHEM-RAPID, V6, P761

[10]

HALL PG, 1986, POLYM COMMUN, V27, P100

← 1 2 3 →